Elsevier

Chemical Physics

Volume 33, Issue 2, 15 September 1978, Pages 305-312
Chemical Physics

Detailed product energy distributions for exothermic triatomic exchange reactions from a statistical dynamic model

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Abstract

A statistical dynamic model which has been proposed in an earlier publication is refined in order to discuss rotational distributions and applied to some representative examples. It relies on a Franck-Condon type description of the collinear rearrangement. Rotational states are assumed to be “a priori” equally probable. Detailed vibration-rotational distributions for H(D) + F2, H(D) + Cl2, and Cl + H(D)I reactions show good agreement with experimental findings.

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