Localized vibrational modes in proton and deuteron implanted InP single crystals

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Abstract

Infrared absorption spectra of proton and deuteron implanted InP single crystals exhibit four localized vibrational modes with frequencies of 2197, 2212, 2308, 2335 cm-1 and 1600, 1619, 1659, 1678 cm-1, respectively. From a comparison of these mode frequencies with those in other species containing In-H(D) and P-H(D) bonds it is concluded that all four modes observed are due to stretching vibrations of bonds formed between phosphorus and the implanted atoms. The number of vibrating bonds is found to be proportional to the damage density. Annealing experiments indicate a higher thermal stability of the defect configurations giving rise to the two high-energy localized modes.

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