Preparation and magnetic properties of R-Fe-B permanent magnet materials containing Fe3B as the main phase

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Abstract

The coercivity of Nd or Pr containing Fe3B based permanent magnet materials can be improved to approximately μ0Hc = 0.45 T by partial substitutions of the rare earth atoms by Tb or Dy. Full substitution leads to low coercivities due to the formation of the magnetically soft phase R3Fe62B14, which replaces the magnetically hard R2Fe14B phase.

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    However, due to the different phase transformation route, that is, crystallization from the amorphous ribbons, it was observed here that the boride formed is the Fe3B. Others works [36–46], also highlighted the formation of Fe3B during the crystallization of Fe-based amorphous alloys containing boron, hence, justifying the absence of Cr2B in the crystallized condition. It is worth noticing that in all the boride phases observed in this work it is likely that the element Cr is also present substituting Fe, that is, with Cr atoms partly occupying Fe-sites.

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