Elsevier

Polyhedron

Volume 6, Issue 5, 1987, Pages 1157-1159
Polyhedron

Molecular structure of tetrakis[benzenethiolatotrimethylplatinum(IV)], (μ3-SPh)4(PtMe3)4

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Abstract

The crystal structure of the title compound is reported, and the geometry and symmetry of the three-fold bridging by the arylthiolate ligand with two-fold symmetry is assessed. Ptsingle bondS bond lengths are differentiated by only 0.04Å. Crystal data: C36H56Pt4S4, M = 1897.4, tetragonal, space group P43212, a = 14.187(1), c = 40.399(6)Å, U = 8131.11Å3, Z = 8.

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Cited by (14)

  • Stereoisomers of organoplatinum complexes

    2015, Journal of Organometallic Chemistry
    Citation Excerpt :

    Each Pt atom is five coordinated (PtC3Cl2) (Table 5). There are five colorless tetramers, Pt4(μ3-SMe)4(Me)12 trigonal [88], monoclinic [89], tetragonal [90]; and Pt4(μ3-I)4(Me)12 rhombohedral [88] and tetragonal [91] which are isostructural with a cubane type structure. Structure of trigonal Pt4(μ3-SMe)4(Me)12 is shows in Fig. 6 as an example.

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