Elsevier

Polyhedron

Volume 2, Issue 10, 1983, Pages 1025-1029
Polyhedron

Synthesis, properties and crystal structure of bis(thiobenzoato-s) selenium(II)

https://doi.org/10.1016/S0277-5387(00)81449-7Get rights and content

Abstract

The synthesis, properties and crystal structure of bis(thiobenzoato)selenium(II) are described. The complex is formed on interaction of selenium(IV) in acid medium with thiobenzoic acid. It is highly stable towards most metal ions. Crystal structure analysis and ir spectroscopic study indicate that the selenium is covalently bonded to sulphur with weak secondary interactions between selenium and oxygen which complete an S2O2 coordination around selenium. There are no intermolecular interactions in the crystal structure.

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