95Mo NMR investigation on cationic [C5H5Mo(CO)2L2]BF4 complexes (L = group 15 donor ligands☆
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Synthesis, structure and reactivity of complexes containing a transition metal-bismuth bond
2011, Coordination Chemistry ReviewsCitation Excerpt :The crystal structure of the phenyl derivative showed a pseudo-octahedral geometry at iron and an iron-bismuth bond length of 2.570(1) Å, consistent with a largely σ-bonded system. A similar methodology was employed by Levason, who used the THF adducts of the group 6 metal carbonyls and BiPh3 to prepare [(CO)5MBiPh3] (M = Cr, Mo, W), the coordination of BiPh3 to molybdenum carbonyl compounds had previously been reported by Houk and Dobson and also by Schumann [115–119]. The crystal structures of the Mo and W compounds show an octahedral geometry at the metal centre, with BiPh3 occupying an axial position, which is reflected in an increase of the 1JW–C coupling constant for the trans carbonyl.
Molecular molybdenum/bismuth compounds
2006, Inorganica Chimica ActaDevelopments in the coordination chemistry of stibine ligands
2006, Coordination Chemistry ReviewsBismuth annual review covering the year 1991
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