Synthesis and resolution of a novel series of octahedral organometallic complexes chiral at the metal atom

doi:10.1016/0022-328X(85)87156-4

Journal of Organometallic Chemistry

Volume 282, Issue 1, 26 February 1985, Pages C17-C21

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Abstract

A series of chiral complexes of the type [RuX(CO)L(triphos)]X′ (X,X′ = anions, L = neutral ligands, triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane) has been synthesized, and the chemistry studied. The compound [RuMe(CO)(CNBu^t)(triphos)] PF₆ has been resolved, and the absolute configurations of the (+)-enantiomer have been determined.

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Preliminary communicationSynthesis and resolution of a novel series of octahedral organometallic complexes chiral at the metal atom

Abstract

Adv. Organometal. Chem.

Topics Curr. Chem.

J. Organomet. Chem.

Inorg. Chem.

Z. Naturforsch. B

J. Organomet. Chem.

Preliminary communication
Synthesis and resolution of a novel series of octahedral organometallic complexes chiral at the metal atom