Die Kristallstruktur von (CH3)2GaC5H5
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Group 1 cyclopentadienide/group 1,14-tert-butoxide adducts: Ion exchange and coordination polymer formation
2014, PolyhedronCitation Excerpt :Lack of solubility of the s-block compounds of Cp− in suitable inert solvents and their extreme reactivity likely discouraged detailed earlier structural investigations on these salts. Such efforts were not begun in earnest until the 1970s when the first reports on systematic studies of main-group cyclopentadienides and related anions appeared in the literature [7–21]. In the intervening years research on both s- and p-block cyclopentadienides grew exponentially as the result of numerous synthetic-structural [22–48] and computational studies [49–52].
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