Über die Umsetzung von Dimethyldichlorsilan, -german und -stannan mit Propan-1,3-dithiol
Abstract
Reaction of propane-1,3-dithiole with (CH3)2SiCL2, (CH3)2GeCl2 and (CH3)2SNCL2 in the presence of triethylamine results in the formation of the 2-hetero-1,3-dithiacyclohexanes 
Zusammenfassung
Propan-1,3-dithiol liefert bei Gegenwart von Triäthylamin mit (CH32SiCl2, (CH3)2-GeCl2 und (CH3)2SnCl2 die 2-Hetero-1,3-dithiacyklohexane
Literatur (2)
- et al.
Chem. Ber.
(1963) - et al.
Z. Naturforsch.
(1863)
Cited by (13)
Orthogonal reactivity of thiols toward chlorovinylsilanes: Selective thiol-ene chemistry
2015, Tetrahedron LettersCitation Excerpt :As part of our growing efforts to take advantage of this valuable synthetic tool in organosilicon chemistry,13–15 we now report a new and highly chemoselective reaction in which chlorovinylsilanes react exclusively with thiol-terminated molecules via the thiol-ene reaction. Previous reports in the literature have shown that thiol-terminated compounds, which are inherently nucleophilic, react with chlorosilanes by displacing the chloride atom;16,17 however, in the wide breadth of the current study, this was not the case. Additionally, the selective thiol-ene reaction of chlorovinylsilanes results in new thioether-substituted chlorosilanes, which may be very useful in organic synthesis as well as organometallic and materials chemistry.
A convenient preparation of arylthiostannanes
1992, Tetrahedron LettersHigh yield preparation of cyclic disulfides using alkyltin thiolates
1986, Tetrahedron LettersA General, high-yield preparation of thiosulfinate esters using organotin precursors
1983, Tetrahedron Letters