Effects of temperature and pressure on the molecular and electronic structure of N,N′-ethylenebis(salicylideneiminato)nitrosyliron, Fe(NO)(salen)
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Cited by (54)
Reactivity and structure of complexes of small molecules: Nitric oxide
2021, Comprehensive Coordination Chemistry IIIPressure effect investigations on spin-crossover coordination compounds
2018, Comptes Rendus ChimieCitation Excerpt :For this reason, pressure tuning the spin state of SCO compounds has been a valuable experimental tool since the early stages of SCO research and continues to attract significant attention from researchers. High-pressure spectroscopic studies of Drickamer and colleagues and Ferraro and colleagues [2–20] in the 1960–1970 have already addressed the SCO phenomenon using Mössbauer, ultraviolet–visible (UV–vis) and infrared (IR) spectroscopies associated with either piston–cylinder or anvil-type pressure cells. High-pressure investigations (primarily using Mössbauer spectroscopic detection) were then taken up in the 1980s by various study groups [21–41].
Mono- and dinuclear non-heme iron-nitrosyl complexes: Models for key intermediates in bacterial nitric oxide reductases
2013, Coordination Chemistry ReviewsCitation Excerpt :Most commonly, non-heme iron–nitrosyl complexes are found as {Fe–NO}7 species, using the classic Enemark and Feltham notation [36], formed from the reaction of an iron(II) precursor complex with the radical diatomic NO. Depending on the specific coordination environment, these species can exist in either the high-spin (S = 3/2) or low-spin (S = 1/2) ground state (vide infra). Interestingly, some of the very first non-heme iron–nitrosyls characterized exhibit temperature-dependent spin-crossover behavior [37–39]. The {Fe–NO}7 complexes [Fe(salen)(NO)] and [Fe(TMC)(NO)](BF4)2 were first isolated in the mid 1900s and show S = 3/2 ground states at room temperature, but shift to S = 1/2 under cryogenic conditions or high pressures.
Syntheses, structures, electrochemical measurements and magnetic properties of two iron(III) complexes derived from N,N′-o-phenylenebis(3- ethoxysalicylaldimine)
2011, Journal of Molecular StructureCitation Excerpt :The average FeO bond length is known to be insensitive to the spin state of the iron(III), while dependency of the spin state on Fe−N bond distances has been observed for some cases [9–26]. The Fe−N bond lengths of the FeIII Schiff base compounds lie usually in two ranges, 1.90–1.96 Å [22–26] and 2.05–2.20 Å [9–20]. The compounds having Fe−N bond distances in the range 1.90–1.96 Å exhibit low spin state [22–26].
A structure-based analysis of the vibrational spectra of nitrosyl ligands in transition-metal coordination complexes and clusters
2011, Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy