The A2[FeX5(H2O)] series of antiferromagnets
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Cited by (55)
A novel iron (III) organic-inorganic hybrid with a thermochromic transition: Synthesis and structural characterisation of the dicystaminium dichloride aquapentachloridoferrate (III), monohydrate (C<inf>4</inf>H<inf>14</inf>N<inf>2</inf>S<inf>2</inf>)<inf>2</inf>[FeCl<inf>5</inf>(H<inf>2</inf>O)]Cl<inf>2</inf>*H<inf>2</inf>O
2019, Journal of Molecular StructureCitation Excerpt :Magnetic susceptibility measurements were carried out in the temperature range 10–300 K with an applied magnetic field of 0.1 T, on nearly 20 mg of selected crystals of the title compound with a Quantum Design MPMS-XL-5 SQUID magnetometer. The anionic [FeCl5(H2O)]2- complex given in Fig. 3, shows as expected [21,32,41–44] an iron (III) in a slightly distorted octahedral conformation. The selected bond distances and angles both at 120 K and 296 K are presented in Table 2, along with the changes in the interatomic distances from high to low temperature.
Magnetic phase diagram of the low-anisotropy antiferromagnet Cs<inf>2</inf>FeCl<inf>5</inf>·H<inf>2</inf>O
2015, Journal of Magnetism and Magnetic MaterialsCitation Excerpt :Antiferromagnets of the family A2FeCl5·H2O (A=K, Rb, Cs) have a very low anisotropy and Néel temperatures ranging from 6.6 K (Cs) to 15 K (K) [1].
Superexchange interaction enhanced through spin delocalisation in Rb<inf>2</inf>FeBr<inf>5</inf>·H<inf>2</inf>O as studied by polarised neutron diffraction
2003, PolyhedronCitation Excerpt :In this contribution, we present the first results of PND obtained for Rb2FeBr5·H2O compound. Experiments have been performed on a single crystal (about 4×3×1 mm3 in volume) of Rb2FeBr5·H2O which was grown from solution following standard [1]. The crystal structure has been determined previously at room temperature by X-ray diffraction and at low temperature by powder neutron diffraction on deuterated samples [5,12].
Effect of spin delocalisation in K<inf>2</inf>FeCl<inf>5</inf>·H<inf>2</inf>O on its superexchange pathways
2003, Physica B: Condensed MatterInfrared and Raman studies of water molecule normal vibrations in crystalline hydrates which form the chain structures
2003, Journal of Molecular StructureInfluence of the chain and layer structure of Fe(III) and In(III) aqua-pentachloro-complexes on the bending vibrations of water molecules
2002, Journal of Molecular Structure