organic compounds
The title compound, 2C6H16N+.C20H14O12Si22-, was prepared by the reaction of (R,R)-(+)-tartaric acid with triethoxyphenylsilane and triethylamine in ethanol. The structure of this optically active pentacoordinate phenylsilicate consists of independent bis[(R,R)-tartrato]diphenyldisilicate anions and triethylammonium cations. In the crystal, the two Si atoms are five-coordinate and the geometry of each of the Si atoms is distorted from the trigonal bipyramid towards the square pyramid along the Berry pseudorotational coordinate by ca 9.8 and 8.9% respectively.
Supporting information
Crystallographic Information File (CIF) |
CCDC reference: 128257