Summary
The paper examines the possibility of relating the RM values of a substance in a non-ideal binary solvent mixture used as the mobile phase to the adsorption characteristics of the individual solvents on the adsorbents used. The theoretically calculated\(R_{M_{1,2} } = f(\varphi _1 )\) relationship (where ϕ1 is the volume fraction of component 1 of the binary solvent mixture in the volume phase) was compared to actual data calculated by measuring the RF values of various substances chromatographed on silica gels using thin-layer adsorption chromatography. A good agreement between the theoretical and experimental data was found.
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Różyło, J.K. Interpretation of the thin-layer chromatographic process using non-ideal two-component mixtures as the mobile phase. Chromatographia 8, 390–394 (1975). https://doi.org/10.1007/BF02269086
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DOI: https://doi.org/10.1007/BF02269086