Summary
Isomeric hydrocarbons with molecules having similar geometry but differing in the electron density distribution were separated on capillary columns packed with barium sulphate, a non-porous ionic adsorbent. Samples of BaSO4 were washed free of foreign ions and modified by solutions of alkaline metal halides. The selectivity of the separation of unsaturated and aromatic hydrocarbons can be controlled by varying the conditions of the BaSO4 treatment. Capillary columns packed with the ionic adsorbent were successfully used to separate all xylene and butene isomers, as well as isomers of cis and trans octene-2.
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References
A. V. Kiselev, V. I. Nazarova, K. D. Shcherbakova, Chromatographia,14, 148 (1981).
A. V. Kiselev, in “Fizicheskaya Khimiya. Sovremennye Problemy” (Physical Chemistry. Modern Problems), Ed.Ya. A. Kolotyrkin, Khimiya Press, Moscow, 1982, vol. 2, p. 180.
I. Halász, C. Horváth, Nature (London),197, 71 (1963).
Th. Welsch, W. Engewald, J. Poerschmann, J. Chromatogr.,148, 143 (1978).
A. V. Kiselev, V. I. Nazarova, K. D. Shcherbakova, E. Smolkova-Keulemansova, L. Feltl, Chromatographia,17, 533 (1983).
C. Vidal-Madjar, G. Guiochon, J. Chromatogr. Sci.,9, 664 (1971).
A. V. Kiselev, N. V. Kovaleva, Yu. S. Nikitin, J. Chromatogr.,58, 19 (1971).
A. Di Corcia, A. Liberti, R. Samperi, J. Chromatogr.,122, 459 (1976).
A. V. Kiselev, Ya. I. Yashin, “Gazo-Adsorbtsionnaya Khromatografiya” (Gas-Adsorption Chromatography), Nauka Press, Moscow, 1967.
A. V. Kiselev, Ya. I. Yashin, “Adsorbtsionnaya Gazovaya i Zhidkostnaya Khromatografiya” (Gas-Solid and Liquid-Solid Chromatography), Khimiya Press, Moscow, 1979.
L. D. Belyakova, A. M. Kiselev, G. A. Soloyan, Chromatographia,3, 254 (1970).
L. D. Belyakova, A. M. Kalpakian, A. V. Kiselev, Chromatographia,7, 14 (1974).
W. Szczepaniak, J. Nawrocki, W. Wasiak, Chromatographia,12, 559 (1979).
T. I. Wishousky, R. L. Grob, A. G. Zacchei, J. Chromatogr.,249, 1 (1982).
K. Naito, R. Kurita, S. Moriguchi, S. Takei, J. Chromatogr.,246, 199 (1982).
K. Naito, M. Endo, S. Moriguchi, S. Takei, J. Chromatogr.,253, 205 (1982).
A. V. Kiselev, J. Chem. Technol. and Biotechnol.,29, 673 (1979).
L. V. C. Rees, Ed., Proceedings of the Fifth International Conference on Zeolites, Heyden, London, 1980.
A. V. Kiselev, K. D. Shcherbakova, Ya. I. Yashin, Zurn. Strukturnoi Khim.,10, 951 (1969).
W. Schneider, J. C. Frohne, H. Bruderreck, J. Chromatogr.,155, 311 (1978).
G. Schomburg, F. Weeke, F. Müller, M. Oréans, Chromatographia,16, 87 (1982).
P. P. Pawar, K. P. Naikwadi, S. M. Likhite, B. V. Bapat, B. B. Ghatge, J. Chromatogr.,245, 57 (1982).
Z. Witkiewicz, J. Chromatogr.,251, 311 (1982).
Z. P. Vetrova, N. T. Karabanov, Ya. I. Yashin, Dokl. Akad. Nauk SSSR,250, 1165 (1980).
M. S. Vigdergauz, R. V. Vigalok, G. V. Dmitrieva, Uspekhi Khimii,50, 943 (1981).
U. Taramasso, F. Veniale, Chromatographia,2, 239 (1969).
A. I. Zhukova, S. V. Bondarenko, Yu. I. Tarasevich, Kolloidn. Zhurn.,43, 1068 (1981); Ukr. Khim. Zhurn.,46, 370 (1980).
S. P. Wasik, R. L. Brown, Analyt. Chem.,48, 2218 (1976).
I. Hadzistelios, F. Lawton, C. S. G. Phillips, J. Chem. Soc. Dalton Trans.,20, 2159 (1973).
I. Halász, E. Heine, Nature (London),194, 971 (1962).
R. F. Hirsch, R. J. Gaydosh, J. R. Chrétien, J. E. Dubois, Chromatographia,16, 251 (1982).
Z. Krawiec, M. F. Gonnord, G. Guiochon, J. R. Chrétien, Analyt. Chem.,51, 1655 (1979).
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Belyakova, L.D., Kiselev, A.V. & Strokina, L.M. Separation of unsaturated and aromatic hydrocarbons on capillary columns packed with barium sulphate. Chromatographia 20, 519–524 (1985). https://doi.org/10.1007/BF02312169
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DOI: https://doi.org/10.1007/BF02312169