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Are we using the full range of film thickness in capillary-GLC?

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Summary

In most capillary GCL columns the film thickness is almost always the same. In addition to column dimensions, liquid phase and support characteristics, however, the film thickness of a column is of great importance and should be adjusted for the specific problem. Dependence of retention, separation efficiency, inertness, capacity, and thermal stability on film thickness is empirically shown for a 100-fold (1∶100) thickness range. In conclusion, directions are given for determining the appropriate film thickness for the different types of sample and analytical tasks.

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References

  1. K. Grob andG. Grob, J. Chromatogr.125, 471 (1976).

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  2. K. Grob, G. Grob andK. Grob jun., Chromatographia March 1977.

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Grob, K., Grob, K. Are we using the full range of film thickness in capillary-GLC?. Chromatographia 10, 250–255 (1977). https://doi.org/10.1007/BF02274475

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  • DOI: https://doi.org/10.1007/BF02274475

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