Skip to main content
SpringerLink
Log in

Characterization of the interaction between gelatin and a spread monolayer of octadecanoic acid

1. The influence of a gelatin-surfactant solution on the dynamic behaviour of a spread14C-labelled octadecanoic acid monolayer

  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

Using the radio-tracer technique the dynamic behaviour of a14C-octadecanoicacid monolayer spread on a gelatin adsorption layer was investigated. The experimental set-up and conditions are given.

It was shown that the dynamic behaviour significantly differs form that of a14C-octadecanoic-acid monolayer spread on a 10−2 M/dm3 HCl solution.

The differences were explained on the basis of the ionic interactions of the octadecanoic acid monolayer with the gelatin. The aimed blocking of the ionic groups of the gelatin by means of an anionic (SDS) and a cationic (CTAB) surfactant lead to the result that the dynamic behaviour of the spread monolayer did not differ from that spread on a gelatin-free aqueous solution. So the addition of SDS and CTAB to the gelatin solution dependent upon the concentration used, leads to mixed surfactant/gelatin complexes or to the formation of a multilayer system consisting on an octadecanoic monolayer on the top of a gelatin-surfactant complex adsorption layer.

The restriction of the interaction between the spread monolayer and the gelatin by both surfactants could be explained as the result of a sterical hindrance.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Pankhurst KGA, Smith RCM (1947) Trans Faraday Soc 43:511

    Google Scholar 

  2. Ikeda S, Isemura T (1959) Bull Chem Soc Japan 32:659

    Google Scholar 

  3. Tamaki K, Tamamushi B (1955) Bull Chem Soc Japan 28:555

    Google Scholar 

  4. Knox WJ, Wright JF (1965) J Coll Sci 20:177

    Google Scholar 

  5. Knox WJ, Parshall TD (1970) J Coll Interf Sci 33:16

    Google Scholar 

  6. Tavernier BH (1983) J Coll Interf Sci 93:419

    Google Scholar 

  7. Arora JPS, Soam D, Singh SP, Kumar R (1984) Tenside, Detergents 21:87

    Google Scholar 

  8. Trapeznikov AA, Vins VG, Sirokova TJu (1981) Kolloid Z, USSR 43:322

    Google Scholar 

  9. Knox WJ, Parshall TD (1972) J Coll Interf Sci 40:290

    Google Scholar 

  10. Wüstneck R, Zastrow L, Kretzschmar G (1985) Kolloid Z, USSR 47:462

    Google Scholar 

  11. Wüstneck R, Zastrow L, Kretzschmar G (1985) Kolloid Z, USSR 47:462

    Google Scholar 

  12. Wüstneck R, Krotov VV, Ziller M (1984) Coll & Polym Sci 262:67

    Google Scholar 

  13. Wüstneck R, Hermel H, Kretzschmar G (1984) Coll & Polym Sci 262:827

    Google Scholar 

  14. Vollhardt D, Zastrow L, Wüstneck R (1978) Coll & Polym Sci 256:973

    Google Scholar 

  15. Lunkenheimer K, Miller R (1979) Tenside, Detergents 16:312

    Google Scholar 

  16. Miller R (1983) Coll & Polym Sci 261:441

    Google Scholar 

  17. Hermel H (1981) J Signal AM 9:55

    Google Scholar 

  18. Zorn H, Selden P (1961) Österr Chem Z 62:37

    Google Scholar 

  19. Wüstneck R, Fruhner H (1981) Coll & Polym Sci 259:1228

    Google Scholar 

  20. Vollhardt D, Wüstneck R, Zastrow L (1978) Coll & Polym Sci 256:983

    Google Scholar 

  21. Steinbach H, Sucker C (1972) Kolloid Z u Z Polym 250:812

    Google Scholar 

  22. Steinbach H, Sucker C (1973) Kolloid Z u Z Polym 251:236

    Google Scholar 

  23. Fukushima K, Murata Y, Nishikido N, Sugihara G, Tanaka M (1981) Bull Chem Soc Japan 54:3122

    Google Scholar 

  24. Wüstneck R, Kretzschmar G, Zastrow L, Kolloid Z, USSR, in press

  25. Nordwig A, Hörmann H, Kühn K, Grassmann W (1961) Hop-pe-Seylers Z physiol Chem 325:242

    Google Scholar 

  26. Wüstneck R (1984) Coll & Polym Sci 262:821

    Google Scholar 

Download references

Author information

Author notes

  1. L. Zastrow

    Present address: Central Institute of Organic Chemistry, Academy of Sciences of the GDR, Berlin, G.D.R.

Authors and Affiliations

  1. Central Institute of Organic Chemistry, Academy of Sciences of the GDR, Berlin, G.D.R.

    R. Wüstneck & G. Kretzschmar

Authors
  1. L. Zastrow
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. Wüstneck
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. Kretzschmar
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zastrow, L., Wüstneck, R. & Kretzschmar, G. Characterization of the interaction between gelatin and a spread monolayer of octadecanoic acid. Colloid & Polymer Sci 263, 749–755 (1985). https://doi.org/10.1007/BF01422858

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01422858

Key words

Search

Navigation