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Coordination ability of the heterocycles 1,3-dithia-2-arsa- and -stiba-cyclopentanes towards sulfur containing ligands, part II. Diheterocyclic dithiocarbamate complexes. X-ray structure of the 4-morpholinecarbodithioate of 1,3-dithia-2-arsa-cyclopentane

Koordinationsvermögen von 1,3-Dithia-2-arsa- und -stiba-cyclopentanen gegenüber Schwefel-enthaltenden Liganden, 2. Mitt.: Diheterocyclische dithiocarbamat-Komplexe Röntgenstrukturanalyse des 4-Morpholinocarbodithioats von 1,3-Dithia-2-arsa-cyclopentan

  • Organische Chemie Und Biochemie
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Summary

A series of diheterocyclic dithiocarbamate complexes of the typeRNCS2 MS2C2H4, whereR=pyrrolidyl, 3-pyrrolyl, 4-morpholyl, 3-methlpiperidyl andM=As or Sb were obtained and characterized by IR,1H, and13C-NMR, mass spectroscopy and elemental analyses. The X-ray crystal structure determination of the 4-morpholinecarbodithioate of 1,3-dithia-2-arsa-cyclopentane shows a monodentate behaviour of theRNCS2 entity.

Zusammenfassung

Es wurden eine Reihe von diheterocyclischen Dithiocarbamat-Komplexen des TypsRNCS2 MS2C2H4 mitR=Pyrrolidyl, 3-Pyrrolyl, 4-Morpholyl, 3-Methylpiperidyl undM=As oder Sb hergestellt und mittels IR,1H- und13C-NMR, MS und Elementaranalysen charakterisiert. Die Röntgenstrukturanalyse des 4-Morpholinocarbodithioats von 1,3-Dithia-2-arsa-cyclopentan zeigt ein monodentates Verhalten derRNCS2-Einheit.

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Authors and Affiliations

  1. Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, D.F., México

    Raymundo Cea-Olivares & Rubén Alfredo Toscano

  2. Facultad de Química, Universidad Autónoma de Morelos, Av. Universidad, Cuernavaca, Morelos, México

    Marcela López & Patricia García

Authors
  1. Raymundo Cea-Olivares
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  2. Rubén Alfredo Toscano
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  3. Marcela López
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  4. Patricia García
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Dedicated to Dr. Lydia Rodríguez on the Occasion of her 60th Birthday.

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Cea-Olivares, R., Toscano, R.A., López, M. et al. Coordination ability of the heterocycles 1,3-dithia-2-arsa- and -stiba-cyclopentanes towards sulfur containing ligands, part II. Diheterocyclic dithiocarbamate complexes. X-ray structure of the 4-morpholinecarbodithioate of 1,3-dithia-2-arsa-cyclopentane. Monatsh Chem 124, 177–183 (1993). https://doi.org/10.1007/BF00808677

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  • DOI: https://doi.org/10.1007/BF00808677

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