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Neue Oxocadmate der Alkalimetalle: K6[CdO4],Rb6[CdO4], Rb2CdO2 und Rb2Cd2O3

New oxocadmates of the alkali metals: K6[CdO4], Rb6[CdO4], Rb2CdO2 and Rb2Cd2O3

  • Anorganische Und Physikalische Chemie
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Abstract

The crystal structure of K6[CdO4] and Rb2CdO2 has been determined from single crystal X-ray diffraction data and refined toR=0.058 (K6[CdO4]) andR=0.088 (Rb2CdO2). K6[CdO4] crystallizes hexagonal, space group P63mc with lattice constantsa=867.42 (6),c=665.5 (1) pm,c/a=0.767 andZ=2. It is isotypic with Na6[ZnO4]. Rb2CdO2 is orthorhombic, space group Pbcn witha=1045.0 (2),b=629.1 (1),c=618.3 (1) pm,Z=4, and crystallizes with the K2CdO2 structure type. The crystal structures can be deduced from the motif of a closest packed arrangement of O2− with hexagonal (K6[CdO4]) or cubic (Rb2CdO2) stacking. The tetrahedra occupied by Cd2+ are isolated (K6[CdO4]) or edge-shared (formation of infinite SiS2-like chains [CdO4/2]) (Rb2CdO2). The powder diffraction pattern of Rb6[CdO4] [a=906.6 (1),c=694.3 (1) pm] and Rb2Cd2O3 [a=642.6 (2),b=679.0 (1),c=667.9 (2) pm, β=115.2 (1)] confirm isotypie with K6[CdO4] and K2Cd2O3 respectively.

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Literatur

  1. Scholder R (1969) Angew Chem 66: 461

    Google Scholar 

  2. von Schnering HG (1962) Z Anorg Allg Chem 314: 144

    Google Scholar 

  3. Vielhaber E, Hoppe R (1970) Rev Chim Miner 6: 169

    Google Scholar 

  4. Norrestam R (1967) Acta Chem Scand 21: 2871

    Google Scholar 

  5. Vielhaber E, Hoppe R (1972) Z Anorg Allg Chem 392: 209

    Google Scholar 

  6. Vielhaber E, Hoppe R (1968) Z Anorg Allg Chem 360: 7

    Google Scholar 

  7. Vielhapper E, Hoppe R (1971) Z Anorg Allg Chem 382: 270

    Google Scholar 

  8. Seipp E, Hoppe R (1985) Z Anorg Allg Chem 530: 117

    Google Scholar 

  9. Vielhaber E, Hoppe R (1965) Z Anorg Allg Chem 338: 209

    Google Scholar 

  10. Brachtel G, Hoppe R (1978) Z Anorg Allg Chem 441: 83

    Google Scholar 

  11. Brachtel G, Hoppe R (1978) Z Anorg Allg Chem 438: 97

    Google Scholar 

  12. DissertationBaier R (1987) Gießen

  13. DissertationSeipp E (1987) Gießen

  14. Kastner P, Hoppe R (1974) Z Anorg Allg Chem 409: 69

    Google Scholar 

  15. Baier R,Hoppe R, in Vorbereitung

  16. Klemm W, Helms A (1939) Z Anorg Allg Chem 242: 33

    Google Scholar 

  17. Hackspill L (1905) CR Acad Sci 141: 106;Hackspill L (1911) Bull Soc Chim Fr 9: 464

    Google Scholar 

  18. Simon A (1970) J Appl Crystallogr 3: 11

    Google Scholar 

  19. Soose J,Meyer G (1980) Programme zur Auswertung von Guinieraufnahmen. Staatsexamensarbeit J Soose, Gießen

  20. Yvon K, Jeitschko W, Parthé E (1977) J Appl Crystallogr 10: 73

    Google Scholar 

  21. Sheldrick GM (1976) SHELX 76. Program for crystal structure determination. University of Cambridge

  22. Hoppe R (1980) Angew Chem 92: 106

    Google Scholar 

  23. Hoppe R (1979) Z Kristallogr 150: 23

    Google Scholar 

  24. Shannon RD,Gumerman PS (1976) Central Research Department E.I. DuPont De Nemours, Wilmington, Delaware, U.S.A.

  25. Hoppe R (1966) Angew Chem 78: 52 (1966);Hoppe R (1966) Angew Chem Int Ed 5: 95;Hoppe R (1970) Angew Chem 82: 7 (1970);Hoppe R (1970) Angew Chem Int Ed 9: 25;Hoppe R (1970) Advan Fluorine Chem 6: 387;Hoppe R (1973) Izvj Jugoslav Centr Krist 8: 21;Hoppe R (1975) In: Crystal structure and chemical bonding in inorganic chemistry. Amsterdam, pp 127 ff

    Google Scholar 

  26. Darriet B, Devalette M, Roulleau F, Avallet M (1974) Acta Cryst B 30: 2667

    Google Scholar 

  27. Sommer H, Hoppe R (1978) Z Anorg Allg Chem 443: 201

    Google Scholar 

  28. Klepp K, Bronger W (1983) Z Naturforsch 38 b: 12

    Google Scholar 

  29. Klepp K, Bronger W (1983) Rev Chim Minér t 20: 682

    Google Scholar 

  30. Frit B, Holmberg B (1970) Acta Cryst B 26: 16

    Google Scholar 

  31. Schleid Th,Meyer G (1986) J Less Common Metals (im Druck)

  32. Schleid Th,Meyer G, unveröffentlicht

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Authors and Affiliations

  1. Institut für Anorganische und Analytische Chemie I, Justus-Liebig-Universität Gießen, D-6300, Gießen, Bundesrepublik Deutschland

    Roland Baier, Erhard Seipp & Rudolf Hoppe

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  1. Roland Baier
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  2. Erhard Seipp
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  3. Rudolf Hoppe
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Herrn Prof. Dr.Gutman zum 65. Geburtstag gewidmet.

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Baier, R., Seipp, E. & Hoppe, R. Neue Oxocadmate der Alkalimetalle: K6[CdO4],Rb6[CdO4], Rb2CdO2 und Rb2Cd2O3 . Monatsh Chem 118, 677–690 (1987). https://doi.org/10.1007/BF00809217

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  • DOI: https://doi.org/10.1007/BF00809217

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