Skip to main content
SpringerLink
Log in

1,5-bis-(2,3-dihydroxy-phenylmethylene)-thiocarbohydrazone as reagent for the spectrofluorimetric determination of nanogram amounts of gallium

  • Original Papers
  • Published:
Microchimica Acta Aims and scope Submit manuscript

Abstract

A method is developed for the spectrofluorimetric determination of nanogram amounts of gallium using 1,5-bis-(2,3-dihydroxy-phenylmethylene)-thiocarbohydrazone in a 60% (v/v) ethanol-water medium phthalate buffered to pH* 3.5 (λex 400 nm, λem 493 nm, corrected), which allows the determination of 20–100 and 120–600 μg/ml with 1.32 and 0.80 as relative error, respectively, and 5.1 ng·ml−1 as detection limit. Interferences have been evaluated and the method applied to the determination of gallium in samples of bovine liver, heart and kidney.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. Kurzer, M. Wilkinson,Chem. Rev. 1970,70, 111.

    PubMed  Google Scholar 

  2. S. Rhee,J. Pharm. Soc. Korea 1972,16, 162.

    Google Scholar 

  3. J. Bonilla Abascal, A. García de Torres, J. Cano Pavón,Microchem. J. 1983,28, 132.

    Google Scholar 

  4. A. T. Pilipenko, E. N. Arendaryuk,Ukr. Khim. Zh. 1979,45, 562;Chem. Abstr. 1979,91,116709w.

    Google Scholar 

  5. M. T. Montaña González, J. L. Gómez Ariza,An. Quim. 1984,80B, 129.

    Google Scholar 

  6. D. Rosales, J. L. Gómez Ariza,Anal. Chim. Acta 1985,169, 367.

    Google Scholar 

  7. F. J. Barragán de la Rosa, J. L. Gómez Ariza, F. Pino,Talanta 1983,30, 555.

    Google Scholar 

  8. D. Rosales, G. González, J. L. Gómez Ariza,Talanta 1985,32, 467.

    Google Scholar 

  9. F. J. Barragán de la Rosa, J. L. Gómez Ariza, F. Pino,Mikrochim. Acta [Wien] 1983,II, 455.

    Google Scholar 

  10. S. Barbus, C. G. Macarovici,Rev. Roum. Chim. 1981,26, 1255.

    Google Scholar 

  11. N. A. Mote, M. A. Anuse, N. B. Chavan,Curr. Sci. 1983,52, 69.

    Google Scholar 

  12. J. Pramanik, J. P. Ghosh, M. Mazumdar,J. Indian Chem. 1981,58, 235.

    Google Scholar 

  13. P. C. Mitra, S. C. Shome,J. Indian Chem. Soc. 1983,60, 250.

    Google Scholar 

  14. E. Ureña, A. García de Torres, J. M. Cano Pavón, J. L. Gómez Ariza,Anal. Chem. 1985,57, 2309.

    PubMed  Google Scholar 

  15. N. Scott, D. E. Carter,Anal. Chem. 1987,59, 888.

    PubMed  Google Scholar 

  16. A. M. Afonso, M. González Dávila, J. J. Santana, F. García Montelongo,Anal. Chim. Acta 1987,202, 207.

    Google Scholar 

  17. A. D. Hill, K. Y. Patterson, C. Veillon, E. R. Morris,Anal. Chem. 1986,58, 2340.

    Google Scholar 

  18. IUPAC Compendium of Analytical Nomenclature: Definitive Rules 1977 (H. M. H. N. Irving, H. Freiser, T. S. West, eds.), Pergamon, Oxford, 1978.

    Google Scholar 

  19. M. M. Hart, R. H. Adamson,Proc. Nat. Acad. Sci. U.S. 1971,68, 1623.

    Google Scholar 

  20. Gallium-67 Imaging (P. B. Hoffer, C. Beckerman, R. E. Henkin, eds.), Wiley, New York, 1978.

    Google Scholar 

  21. R. A. Newman, A. R. Brody, I. H. Krakoff,Cancer 1979,44, 1728.

    PubMed  Google Scholar 

  22. D. P. Kelsen, N. Alcock, S. Yeh, J. Brown, C. Young,Cancer 1980,46, 2009.

    PubMed  Google Scholar 

  23. A. Zweidinger, L. Barnett, C. G. Pitt,Anal. Chem. 1973,8, 1563.

    Google Scholar 

  24. E. Requena, J. J. Laserna, A. Navas, F. García Sánchez,Analyst 1983,108, 933.

    Google Scholar 

  25. A. M. Afonso, J. J. Santana, F. J. García Montelongo,Anal. Lett. 1985,18(A8), 1003.

    Google Scholar 

  26. M. E. Ureã Pozo, A. García de Torres, J. M. Cano Pavón,Anal. Chem. 1987,59, 1129.

    PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Analytical Chemistry, University of La Laguna, E-38204, La Laguna, Tenerife, Spain

    José J. Santana, Melchor González-Dávila, Ana M. Afonso & Francisco García-Montelongo

Authors
  1. José J. Santana
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Melchor González-Dávila
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ana M. Afonso
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Francisco García-Montelongo
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Santana, J.J., González-Dávila, M., Afonso, A.M. et al. 1,5-bis-(2,3-dihydroxy-phenylmethylene)-thiocarbohydrazone as reagent for the spectrofluorimetric determination of nanogram amounts of gallium. Mikrochim Acta 100, 55–61 (1990). https://doi.org/10.1007/BF01244498

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01244498

Key words

Search

Navigation