Abstract
Liquidus phase relationships determined on the join anorthite-forsterite-quartz at 20 kbar show primary phase fields for quartz (q), forsterite (fo), enstatite (en), spinel (sp), anorthite (an), sapphirine (sa), and corundum (cor). Increasing pressure causes (1) thefo andan primary phase fields to contract, (2) theen, q, andcor fields to expand, (3) thefo-en boundary line to move away from the Q apex, (4) theen-q boundary line to move also away from the Q apex but by a smaller amount, and (5) a primary phase field forsa to appear at a pressure between 10 and 20 kbar. Seven liquidus piercing points at 20 kbar have been located as follows:
Crystalline phases | Liquid composition (wt %) | Temperature (°C) |
---|---|---|
sp+sa+cor | An81Fo17Q2 | 1575 |
fo+en+sp | An52Fo39Q9 | 1540 |
en+sp+sa | An59Fo31Q10 | 1490 |
sa+an+cor | An70Fo15Q15 | 1430 |
an+q+cor | An66Fo7Q27 | 1410 |
sa+an+en | An62Fo18Q20 | 1400 |
an+en+q | An59Fo15Q26 | 1380 |
It is concluded that (1) the shift of thefo-en boundary line away from the quartz apex with pressure confirms many other studies showing that melts generated from peridotite source rocks decrease in silica content as pressure increases; (2) even though plagioclase is not a stable phase in peridotite source rocks at pressures above about 10 kbar, it can crystallize from mafic magmas at pressures at least up to 20 kbar; (3) sapphirine crystallizes from mafic magmas at high pressures and may be important in the construction of petrogenetic models based on trace element considerations.
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References
Ackermand D, Seifert F, Schreyer W (1975) Instability of sapphirine at high pressures. Contrib Mineral Petrol 50: 79–92
Albee AL, Ray L (1970) Correction factors for electron-probe microanalysis of silicates, oxides, carbonates, phosphates and silicates. Anal Chem 42: 1408–1414
Andersen O (1915) The system anorthite-forsterite-silica. Am J Sci 39: 407–454
Anonymous (1969) The international practical temperature scale of 1968. Metrologia 5: 35–44
Boyd FR, England JL (1960) Apparatus for phase equilibrium measurements at pressures up to 50 kilobars and temperatures up to 1750°C. J Geophys Res 65: 741–748
Brookins DG, Meyer HOA (1974) Crustal and upper mantle stratigraphy beneath Kansas. Geophys Res Lett 1: 269–272
Dallwitz WB (1968) Co-existing sapphirine and quartz in granulite from Enderby Land, Antarctica. Nature 219: 476–477
Chen C-H, Presnall DC (1975) The system Mg2SiO4−SiO2 at pressures up to 25 kilobars. Am Mineral 60: 398–406
Clark SP Jr, Schairer JF, De Neufville J (1962) Phase relations in the system CaMgSi2O6−CaAl2SiO6−SiO2 at low and high pressure. Carnegie Inst Washington 61: 59–68
Foster WR (1950a) Synthetic sapphirine and its stability field in the system MgO−Al2O3−SiO2. J Am Ceramic Soc 33: 73–84
Foster WR (1950b) Synthetic sapphirine and its stability field in the system MgO−Al2O3−SiO2. J Geol 58: 135–151
Green TH, Ringwood AE (1967) Crystallization of basalt and andesite under high pressure hydrous conditions. Earth Planet Sci Lett 3: 481–489
Grew ES (1980) Sapphirine+quartz association from Archean rocks in Enderby Land, Antarctica. Am Mineral 65: 821–836
Grew ES (1981) Surinamite, taaffeite, and beryllian sapphirine from pegmatites in granulite-facies rocks of Casey Bay, Enderby Land, Antarctica. Am Mineral 66: 1022–1033
Griffin WL, O'Reilly SY (1986) Mantle-derived sapphirine. Mineral Mag 50: 635–640
Irvine TN (1975) Olivine-pyroxene-plagioclase relations in the system Mg2SiO4−CaAl2Si2O8−KAlSi3O8−SiO2 and their bearing on the differentiation of stratiform intrusions. Carnegie Inst Washington 74: 492–500
Keith ML, Schairer JF (1952) The stability field of sapphirine in the system MgO−Al2O3−SiO2. J Geol 60: 181–186
Kornprobst J (1969) Le massif ultrabasique des Beni Bouchera (Rif Interne, Maroc): Etude des péridotítes de haute température et de haute pression, et des pyroxenolites à grenat ou sans grenat, qui leur sont associées. Contrib Mineral Petrol 23: 283–322
Kornprobst J, Piboule M, Boudeulle M, Roux L (1982) Corundumbearing garnet pyroxenites at Beni-Bousera (Morocco): an exceptionally Al-rich clinopyroxene from “grospydites” associated with utramafic rocks. Terra Cognita 2: 257–259
Kushiro I (1968) Compositions of magmas formed by partial zone melting in the earth's upper mantle. J Geophy Res 73: 619–634
Kushiro I, Yoder HS Jr (1966) Anorthite-forsterite and anorthite-enstatite reactions and their bearing on the basalt-eclogite transformation. J Petrol 7: 337–362
Longhi J (1987) Liquidus equilibria and solid solution in the system CaAl2Si2O8−Mg2SiO4−CaSiO3−SiO2 at low pressure. Am J Sci 287: 265–331
Meng LK, Moore JM Jr (1972) Sapphirine-bearing rocks from Wilson Lake, Labrador. Can Mineral 11: 777–790
Meyer HOA, Brookins DG (1976) Sapphirine, sillimanite and garnet in granulite xenoliths from Stockdale kimberlite, Kansas. Am Mineral 61: 1194–1202
Morse SA, Talley JH (1971) Sapphirine reactions in deep-seated granulites near Wilson Lake, Central Labrador, Canada. Earth Planet Sci Lett 10: 325–328
O'Hara MJ (1965) Primary magmas and the origin of basalts. Scott J Geol 1: 19–40
O'Hara MJ (1968) The bearing of phase equilibria studies in synthetic and natural systems in the origin and evolution of basic and ultrabasic rocks. Earth Sci Rev 4: 69–133
O'Hara MJ, Yoder HS Jr (1967) Formation and fractionation of basic magmas at high pressures. Scott J Geol 3: 67–117
Presnall DC (1966) The join forsterite-diopside-iron oxide and its bearing on the crystallization of basaltic and ultramafic magmas. Am J Sci 264: 753–809
Presnall DC (1976) Alumina content of enstatite as a geobarometer for plagioclase and spinel lherzolites. Am Mineral 61: 582–588
Presnall DC, Hoover JD (1987) High pressure phase equilibrium constraints on the origin of mid-ocean ridge basalts. In: Mysen BO (ed) Magmatic processes: physicochemical principles. Geochem Soc Spec Pub 1: 75–89
Presnall DC, Simmons CL, Porath H (1972) Changes in electrical conductivity of a synthetic basalt during melting. J Geophys Res 77: 5665–5672
Presnall DC, Brenner NL, O'Donnell TH (1973) Drift of Pt/Pt10Rh and W3Re/W25Re thermocouples in single stage piston-cylinder apparatus. Am Mineral 58: 771–777
Presnall DC, Dixon SA, Dixon JR, O'Donnell TH, Brenner NL, Schrock RL, Dycus DW (1978) Liquidus phase relations on the join diopside-forsterite-anorthite from 1 atm to 20 kbar: their bearing on the generation and crystallization of basaltic magma. Contrib Mineral Petrol 66: 203–220
Presnall DC, Dixon JR, O'Donnell TH, Dixon SA (1979) Generation of mid-ocean ridge tholeiites. J Petrol 20: 3–35
Sen G, Presnall DC (1984) Liquidus phase relationships on the join anorthite-forsterite-quartz at 10 kbar with applications to basalt petrogenesis. Contrib Mineral Petrol 85: 404–408
Stolper E, (1980) A phase diagram for mid-ocean ridge basalts: preliminary results and implications for petrogenesis. Contrib Mineral Petrol 74: 13–27
Taylor HCJ (1973) Melting relations in the system MgO−Al2O3−SiO2 at 15 kb. Geol Soc Am Bull 84: 1335–1348
Yoder HS Jr, Tilley CE (1962) Origin of basalt magmas: an experimental study of natural and synthetic rock systems. J Petrol 3: 342–532
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Contribution No. 588, Geosciences Program, The University of Texas at Dallas
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Liu, TC., Presnall, D.C. Liquidus phase relationships on the join anorthiteforsterite-quartz at 20 kbar with applications to basalt petrogenesis and igneous sapphirine. Contr. Mineral. and Petrol. 104, 735–742 (1990). https://doi.org/10.1007/BF01167290
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DOI: https://doi.org/10.1007/BF01167290