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Hydrocarbon-derived carbonate buildups of the northern Gulf of Mexico continental slope: A review of submersible investigations

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Abstract

Hydrocarbon-derived and microbially mediated authigenic carbonates occur over the entire depth range of the northern Gulf of Mexico slope. These carbonates consist of nodules and incipient nodules in surface sediments, hardgrounds and isolated slabs, and moundlike buildups of up to 10–20 m relief above the surrounding seafloor. The authigenic carbonates are characterized byδ 13C negative values in the range −18‰ to −55‰ (PDB) suggesting mixing of seawater carbon with13C-depleted carbon sources ranging from crude oil to biogenic methane. Near the shelf edge, carbonates are “diluted” with biogenic material produced by reefs—bioherms developed at low sea level stands. Fossil-poor carbonates over salt diapirs of the upper and middle slope formed in the shallow subsurface and have been exhumed by the combined processes of uplift and physical erosion. Middle and lower slope carbonates are generally rich in fossil shells of chemosynthetic organisms. Mg calcite pelloidal matrix and acicular to botryoidal aragonitic void-filling cements are common petrographic features of these hydrocarbonderived carbonates. At two sites carbonates are mixed with barite.

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References

  • Aharon P, Roberts HH, Sassen R, Wheeler CW, and Feng JH (1989) An isotope study of cold vent deposits from the continental slope, Gulf of Mexico: Progress report. Geological Society of America Abstracts with Programs 21:A273

    Google Scholar 

  • Aharon P, Roberts HH, Sassen R, and Larkin J (1990) Stable isotopes and petrology of chimneys and calcareous fauna from hydrocarbon vents on the Gulf of Mexico slope. Geological Society of America Abstracts with Programs 22:A208

    Google Scholar 

  • Aharon P, Roberts HH, and Snelling R (1992a) Submarine venting of brines in the deep Gulf of Mexico: Observations and geochemistry. Geology 20:483–486

    Google Scholar 

  • Aharon P, Graber ER, and Roberts HH (1992b) Dissolved carbon andδ 13C anomalies in the water column caused by hydrocarbon seeps on the northwestern Gulf of Mexico slope. Geo-Marine Letters 12:33–40

    Google Scholar 

  • Aharon P, Schwarcz HP, Roberts HH, and Valastro S (1993) A feasibility study of the chronology of submarine venting in the northern Gulf of Mexico by radiometric isotope techniques. Geological Society of America Abstracts with Programs 25:A443

    Google Scholar 

  • Beauchamp B and Savard M (1992) Cretaceous chemosynthetic carbonate mounds in the Canadian Arctic. Palaios 7:434–450

    Google Scholar 

  • Berner RA (1971) Principles of Chemical Sedimentology. New York: McGraw-Hill 240 pp

    Google Scholar 

  • Bright TJ (1977) Coral reefs, nepheloid layers, gas seeps, and brine flows on hard-banks in the northwestern Gulf of Mexico. Proceedings, 3rd International Coral Reef Symposium 1:39–46

    Google Scholar 

  • Brooks JM, Kennicutt MC II, Bidigare RR, and Fay RR (1985) Hydrates, oil seepage, and chemosynthetic ecosystems on the Gulf of Mexico slope. EOS, Transaction American Geophysical Union 656:10

    Google Scholar 

  • Brooks JM, Wiesenburg DA, Roberts H, Carney RS, MacDonald IR, Fisher CR, Guinasso NL Jr, Sager WW, McDonald SJ, Burke RA Jr, Aharon P, and Bright TJ (1990) Salt, seeps and synbiosis in the Gulf of Mexico; a preliminary report of deepwater discoveries usingDSV Alvin. EOS 71:1772–1773

    Google Scholar 

  • Bryant WR, Simmons GR, and Grin P (1991) The morphology and evolution of basins on the continental slope, northwest Gulf of Mexico. Gulf Coast Association of Geological Societies Transactions 41:73–82

    Google Scholar 

  • Campbell KJ, Hooper JR, and Prior DB (1985) Engineering implications of deep water geologic and soil conditions, Texas—Louisiana slope. Proceedings, 18th Annual Offshore Technology Conference pp 225–232

  • Coleman JM, Prior DB, and Lindsay JF (1983) Deltaic influences on shelf edge instability process. In: Stanley DJ and Moore GT (Eds.), The Shelfbreak: Critical Interface on Continental Margins. Society of Economic Paleontoogists and Mineralogists Special Publication 33:121–137

    Google Scholar 

  • Corliss JB, Dymond J, Gordon LI, Edmond RP, van Herzen RP, Ballard RD, Green, Williams D, Bainbridge A, Crane K, and van Handel TH (1979) Submarine thermal springs on the Galapagos Rift. Science 203:1073–1083

    Google Scholar 

  • Cunnings ER and Shrock RR (1928) Niagaran coral reefs of Indiana and adjacent states and their stratigraphic relations. Geologic Society of America Bulletin 39:579–619

    Google Scholar 

  • Fang J (1991) Isotopic evidence for petroleum-derived carbonates in the Gulf of Mexico. Gulf Coast Association of Geological Societies Transactions 41:276–282

    Google Scholar 

  • Faugères JC, Gonthier E, Griboulard R, Jollivet D, and Vernette G (1990) Morphology microphysiography, sedimentary, and biology patterns of surficial deposits in the south Barbados prism: record of recent and present active tectonics. Proceedings of the Ocean Drilling Program, Scientific Results 110:111–126

    Google Scholar 

  • Ferrell RE and Aharon P (1994) Mineral assemblages occurring around hydrocarbon vents in the northern Gulf of Mexico. Geo-Marine Letters 14:74–80

    Google Scholar 

  • Galimov EM (1980)13C/12C in Kerogen. In: Durand B (Ed.), Kerogen, Insoluble Organic Matter from Sedimentary Rocks. Paris: Editions Technip pp 271–299

    Google Scholar 

  • Ginsburg RN and James NP (1976) Submarine botryoidal aragonite in Holocene reef limestones, Belize. Geology 4:431–436

    Google Scholar 

  • Graber ER, Aharon P, and Roberts HH (1990) Pore water carbonate chemistry from hydrocarbon vents on the Gulf of Mexico slope. Geological Society of America Abstracts with Programs 22:A208

    Google Scholar 

  • Hamamoto T and Horikoshi K (1993) Deep-sea microbiology research within the Deepstar program. Journal of Marine Biotechnology 1:119–124

    Google Scholar 

  • Hamilton P (1990) Deep currents in the Gulf of Mexico. Journal of Geophysical Research 20:1087–1104

    Google Scholar 

  • Hovland M and Judd AG (1988) Seabed pockmarks and seepages: Impact on geology, biology and the marine environment. London: Graham and Trotman 293 pp

    Google Scholar 

  • Hovland M, Talbot MR, Quale H, Olaussen S, and Aasberg L (1987) Methane-related carbonate cements is pockmark of the North Sea. Journal of Sedimentary Petrology 57:881–892

    Google Scholar 

  • Jannasch HW (1984) Chemosynthesis: The nutritional basis for life at deep-sea vents. Oceanus 27(3):73–78

    Google Scholar 

  • Johnson KS, Childress JJ, Hessler RR, Sakamoto-Arnold CM, and Beehler CL (1988) Chemical and biological interactions in the Rose Garden hydrothermal vent field, Galapagos spreading center. Deep-Sea Research 35:1723–1744

    Google Scholar 

  • Kennicutt MC II, Brooks JM, Bidigare RR, Fay RR, Wade TL, and McDonald TJ (1985) Vent-type taxa in a hydrocarbon seep region on the Louisiana slope. Nature 317:351–353

    Google Scholar 

  • Kulm LD, Suess E, Moore JC, and Carson B (1986) Oregon subduction zone: venting, fauna and carbonates. Science 231:561–566

    Google Scholar 

  • Lallemand SE, Glacon G, Lauriat-Rage A, Fiala-Medioni A, Cadet JP, Beck C, Sibuet M, Iiyama JT, Sakai H, and Taira A (1992) Seafloor mainfestations of fluid seepage at the top of a 2000-metre-deep ridge in the eastern Nankai accretionary wedge: Long-lived venting and tectonic implications. Earth and Planetary Science Letters 109:333–346

    Google Scholar 

  • Land LS and Moore CH (1980) Lithification, micritization and syndepositional diagenesis of biolithites on the Jamaican Island slope. Journal of Sedimentary Petrology 50:357–370

    Google Scholar 

  • Larkin J, Aharon P, Roberts H, and Henk MC (1994)Beggiatoa in microbial mats at hydrocarbon vents in the Gulf of Mexico and Warm Mineral Springs, Florida. Geo-Marine Letters 14:97–103

    Google Scholar 

  • MacDonald IR, Reilly JF II, Guinasso NL Jr, Brooks JM, Carney RS, Bryant WA, and Bright TJ (1990) Chemosynthetic mussels at a brine-filled pockmark in the northern Gulf of Mexico. Science 248:1096–1099

    Google Scholar 

  • Martin RG (1980) Distribution of salt structures in the Gulf of Mexico. United States Geological Survey Map MF-1213:8

    Google Scholar 

  • Neumann AC, Kofoed JW, and Keller GH (1977) Lithoherms in the straits of Florida. Geology 5:4–11

    Google Scholar 

  • Neumann AC, Paull CK, Commeau R, Commeau J, Chanton J, Martens C, Gardemal M, Trumbull W, and Showers W (1988) Abyssal seep site cementation: West Florida Escarpment. American Association of Petroleum Geologists 72:228

    Google Scholar 

  • Neurauter TW and Roberts HH (1992) Seismic and visual observation of seepage related structure on the continental slope, northern Gulf of Mexico. 24th Annual Offshore Technology Conference, paper OTC 6850, Houston, Texas, 4–7 May pp 355–362

    Google Scholar 

  • O'Niel JR, Clayton RN, and Mayeda TK (1969) Oxygen isotope fractionation in divalentmetal carbonates. Journal of Chemical Physics 51:5547–5558

    Google Scholar 

  • Paull CK, Hecker B, Commeau R, Freeman-Lynde RP, Neuman AC, Corso WP, Golubic S, Hook JE, Sikes E, and Curray J (1984) Biological communities at the Florida escarpment resemble hydrothermal vent taxa. Science 226:965–967

    Google Scholar 

  • Paull CK, Chanton JP, Newmann AC, Coston JA, Martens CS, and Showers W (1992) Indicators of methane-derived carbonates and chemosynthetic organic carbon deposits: Examples from the Florida Escarpment. Palaios 7:361–375

    Google Scholar 

  • Rezak R, Bright TJ, and McGrail DW (1985) Reefs and banks of the northwestern Gulf of Mexico—their geological, biological, and physical dynamics. New York: John Wiley & Sons 259 pp

    Google Scholar 

  • Rice DD (1980) Chemical and isotopic evidence of the origins of natural gases in offshore Gulf of Mexico. Gulf Coast Association of Geological Societies Transactions 30:202–213

    Google Scholar 

  • Ritger S, Carson B, and Suess E (1987) Methane-derived authigenic carbonates formed by subduction-induced pore-water expulsion along the Oregon/Washington margin. Geological Society of America Bulletin 98:147–156

    Google Scholar 

  • Roberts HH (1994) Reefs, bioherms, and lithoherms of the northern Gulf of Mexico: The important role of hydrocarbon seeps. Proceeding, 7th International Coral Reef Symposium, University of Guam pp 1133–1140

  • Roberts HH, Sassen R, and Aharon P (1987) Carbonates of the Louisiana continental slope. Proceedings 19th Annual Offshore Technology Conference, Houston, Texas, Paper OTC 5463:373–382

    Google Scholar 

  • Roberts HH, Sassen R, Carney R, and Aharon P (1990) The role of hydrocarbons in creating sediment and small-scale topography on the Louisiana Continental Slope. Gulf Coast Section Society of Economic Paleontologists and Mineralogists, Proceedings 9th Annual Research Conference pp 311–324

  • Roberts HH, Fillon RF, Kohl B, Bouma AH, and Sydow JC (1991) Lithostratigraphy, biostratigraphy, and isotopic investigation of a boring in Main Pass area, Block 303: A calibration of high resolution seismic stratigraphy. Coastal Depositional Systems in the Gulf of Mexico, Quaternary Framework and Environmental Issues, Twelfth Annual Research Conference, Gulf Coast Section. Society of Economic Paleontologists and Mineralogists Special Foundation pp 217–222

  • Roberts HH, Aharon P, and Walsh MM (1992a) Cold-seep carbonates of the Louisiana continental slope-to-basin floor. In: Rezak R and Lavoie D (Eds.), Carbonate Microfabrics. Berlin: Springer-Verlag pp 95–104

    Google Scholar 

  • Roberts HH, Cook DJ, and Sheedlo MK (1992b) Hydrocarbon seeps of the Louisiana Continental Slope: Seismic amplitude signature and sea floor response. Gulf Coast Association of Geological Societies Transactions 42:349–362

    Google Scholar 

  • Sassen R, Roberts HH, Aharon P, Larkin J, Chinn EW, and Carney R (1993) Chemosynthetic bacterial mats at cold hydrocarbon seeps, Gulf of Mexico continental slope. Organic Geochemistry 20(1):77–89

    Google Scholar 

  • Schoell HP (1982) Applications of isotope analysis to petroleum and natural gas research. Spectra 8:32–41

    Google Scholar 

  • Sibuet M, Juniper SK, and Pautot G (1988) Cold-seep benthic communities in the Japan subduction zones: Geological control of community development. Journal of Marine Research 46:333–348

    Google Scholar 

  • Suter JR and Berryhill HL (1985) Late Quaternary shelf margin deltas, northwest Gulf of Mexico. American Association of Petroleum Geologist Bulletin 69:77–91

    Google Scholar 

  • Woodbury HO, Murray IB Jr, Pickford PJ, and Akers WH (1973) Pliocene and Pleistocene depocenters, outer continental shelf, Louisiana and Texas. American Association of Petroleum Geologists Bulletin 57:2428–2439

    Google Scholar 

  • Worall DM and Snelson S (1989) Evolution of the northern Gulf of Mexico, with emphasis on the Cenozoic growth faulting and the role of salt. In: Bally AW and Palmer AR (Eds.), The Geology of North America—An Overview. The Geology of North America A:97–138

    Google Scholar 

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Authors and Affiliations

  1. Coastal Studies Institute, Louisiana State University, 70803, Baton Rouge, Louisiana, USA

    Harry H. Roberts

  2. Department of Geology and Geophysics, Louisiana State University, 70803, Baton Rouge, Louisiana, USA

    Paul Aharon

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  1. Harry H. Roberts
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  2. Paul Aharon
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Roberts, H.H., Aharon, P. Hydrocarbon-derived carbonate buildups of the northern Gulf of Mexico continental slope: A review of submersible investigations. Geo-Marine Letters 14, 135–148 (1994). https://doi.org/10.1007/BF01203725

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  • DOI: https://doi.org/10.1007/BF01203725

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