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Scanning tunneling microscopy on self-assembled calix[4]resorcinarene monolayer adsorbates on Au(111)

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Abstract.

Self-assembled Monolayers of calix[4]resorcinarene receptor molecules on Au(111) were studied by UHV scanning tunneling microscopy and X-ray photoelectron spectroscopy. Highly ordered monolayers were observed with domains oriented at an angle of 60° relative to each other. Molecularly resolved images were investigated and lattice constants found which depended on the preparation solvent. The STM images of two samples, one prepared in 1 mM chloroform/ethyl alcohol adsorbate solution and one in 1 mM hexane adsorbate solution are consistent with having a ×2 and 4×2 lattice, respectively.

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Authors and Affiliations

  1. Institute of Applied Physics, Morgenstelle 10, University of Tuebingen, 72076 Tuebingen, Germany, , , , , , DE

    S. Raible, W. Clauss & D.P. Kern

  2. Institute for Organic Chemistry, Morgenstelle 18, University of Tuebingen, 72076 Tuebingen, Germany, , , , , , DE

    J. Pfeiffer & V. Schurig

  3. Institute for Physical and Theoretical Chemistry, Morgenstelle 8, University of Tuebingen, 72076 Tuebingen, Germany, , , , , , DE

    T. Weiss & W. Goepel

Authors
  1. S. Raible
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  2. J. Pfeiffer
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  3. T. Weiss
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  4. W. Clauss
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  5. W. Goepel
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  6. V. Schurig
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  7. D.P. Kern
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Additional information

Received: 22 September 1999 / Accepted: 28 March 2000 / Published online: 11 May 2000

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Raible, S., Pfeiffer, J., Weiss, T. et al. Scanning tunneling microscopy on self-assembled calix[4]resorcinarene monolayer adsorbates on Au(111) . Appl Phys A 70, 607–611 (2000). https://doi.org/10.1007/s003390050001

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  • DOI: https://doi.org/10.1007/s003390050001

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