Abstract
The work function reduction at a metal surface caused by adsorbed barium and oxygen is already known with the resulting expression for the overall work function being ϕ=ϕS−δϕR. Results from the Re/W alloy-coated cathodes exhibit that δϕR increases with substrate work function with a slope of 1.09 by linear regression. A qualitative explanation of the above results comes from considering the arrangement of barium and oxygen on the surfaces. A charge transfer model is proposed for two-dimensional barium and oxygen lying on a flat non-interacting substrate. Calculation shows that the dipole strength increases with the charge transfer below the intermediate states.
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Ares Fang, C.S., Maloney, C.E. The effect of substrate work function on work function reduction of Re/W alloy-coated impregnated cathodes. Appl. Phys. A 50, 603–607 (1990). https://doi.org/10.1007/BF00323454
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DOI: https://doi.org/10.1007/BF00323454