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Experimental study of quantum size effects in very thin metal films

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Abstract

The influence of the quantum size effect (QSE) in very thin Pd and Au films (0.5<d<10 [nm]) deposited on glass tips is studied by means of field emission at various anode potentials. The thickness-dependent field emission current characteristics show short periodic variations with a period of about 0.3 nm for both Pd and Au. The measured QSE oscillations and their amplitudes differ strongly from those expected qualitatively from model calculations for the smallest thicknesses. A model for the metal film based on a modification of the uniform background model is presented, and the thickness dependence of the conductance and the field emission current density are qualitatively discussed. Possible explanations of some discrepancies between calculations and the measured field emission current characteristics are proposed.

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Stark, D., Zwicknagl, P. Experimental study of quantum size effects in very thin metal films. Appl. Phys. 21, 397–406 (1980). https://doi.org/10.1007/BF00895932

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