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Synthesis of poly[2-(N,N-dimethyl)aminoethyl methacrylate-co-acrylonitrile]

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Summary

Radical copolymerization of 2-(N,N-dimethyl)aminoethyl methacrylate (1) and acrylonitrile (2) initiated by 2,2′-azobis(2-methylpropionitrile) was carried out. The sequence distributions of the copolymers were investigated by 13C NMR spectroscopy. A terminal model was used to interpret the propagation process in the copolymerization. The monomer reactivity ratios in the bulk copolymerization at 45°C were evaluated as r1=1.06 and r2=0.07. Radical reactivity indices and frontier electron densities for 1 and 2 were calculated.

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Authors and Affiliations

  1. Department of Polymer Science and Engineering, Kyoto Institute of Technology, Matsugasaki, 606, Kyoto, Japan

    Masakazu Yoshikawa, Kiyoshi Fujimoto & Toshio Kitao

  2. Department of Chemistry, Sophia University, 7-1 Kioi-cho, Chiyoda-ku, 102, Tokyo, Japan

    Masahiro Rikukawa & Naoya Ogata

  3. Division of Molecular Engineering, Faculty of Engineering, Kyoto University, 606-01, Kyoto, Japan

    Akimoto Tachibana

Authors
  1. Masakazu Yoshikawa
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  2. Kiyoshi Fujimoto
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  3. Toshio Kitao
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  4. Masahiro Rikukawa
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  5. Naoya Ogata
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  6. Akimoto Tachibana
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Yoshikawa, M., Fujimoto, K., Kitao, T. et al. Synthesis of poly[2-(N,N-dimethyl)aminoethyl methacrylate-co-acrylonitrile]. Polymer Bulletin 35, 95–102 (1995). https://doi.org/10.1007/BF00312899

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  • DOI: https://doi.org/10.1007/BF00312899

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