Skip to main content
SpringerLink
Log in

Mechanochemical polymerization in mixtures of diallyl terephthalate and distilled water by ultrasonic irradiation

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

Mechanochemical polymerization in systems of diallyl terephthalate-distilled water has been studied by ultrasonic irradiation at 90°C. An additional effect of distilled water on mechanochemical polymerization of diallyl terephthalate was investigated. When a 1.2 wt % distilled water solution, the conversion of poly(diallyl terephthalate) was the greatest and the initial rate of the polymerization R p was 1.3x10-5 mol/l sec. This polymerization proceeded by a radical mechanism and the primary radicals produced from water molecules by ultrasonic waves. In addition, changes in the iodine value and the weight-average molecular weight of the resulting polymers were proved.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Tanaka, M., Osuka, M., Kuri, T. and Takakuwa, S. (Daiso Co. Ltd.): U. S. Pat. 4, 518, 764 (1985)

    Google Scholar 

  2. Tanaka, M., Kuri, T. and Osuka, M.: Thermosetting Resin 7, 14 (1986)

    Google Scholar 

  3. Fujiwara, H., Okazaki, K. and Goto, K.: J. Polym. Sci., Polym. Phys. Ed. 13, 953 (1975)

    Article  CAS  Google Scholar 

  4. Fujiwara, H. and Goto, K., et al.: Kobunshi Ronbunshu 33, 183 (1976)

    CAS  Google Scholar 

  5. Fujiwara, H. and Goto, K., et al.: Nippon Gomu Kyokaishi 52, 247, (1979)

    CAS  Google Scholar 

  6. Fujiwara, H. and Goto, K., et al.: Polym. J. 13, 927 (1981)

    CAS  Google Scholar 

  7. Fujiwara, H. and Goto, K.: Polym. Bull. 23, 27 (1990)

    Article  CAS  Google Scholar 

  8. Fujiwara, H. and Goto, K.: Kobunshi, Ronbunshu 41, 133 (1984)

    CAS  Google Scholar 

  9. Fujiwara, H., Inoue, I. and Goto, K.: Kobunshi Ronbunshu 37, 741 (1980)

    CAS  Google Scholar 

  10. Fujiwara, H. and Goto, K.: Kobunshi Ronbunshu 39, 481 (1982)

    CAS  Google Scholar 

  11. Edelmann, K.: J. Polym. Sci. 29, 531 (1958)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 16-1, Omiya 5-chome, Asahi-ku, 535, Osaka, Japan

    Hideki Fujiwara & Kunio Goto

Authors
  1. Hideki Fujiwara
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kunio Goto
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fujiwara, H., Goto, K. Mechanochemical polymerization in mixtures of diallyl terephthalate and distilled water by ultrasonic irradiation. Polymer Bulletin 25, 571–574 (1991). https://doi.org/10.1007/BF00293516

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00293516

Keywords

Search

Navigation