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Mechanochemical block copolymerization of poly(vinyl chloride) with methyl methacrylate by ultrasonic irradiation

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Summary

Mechanical degradation and mechanochemical block copolymerization in systems of poly(vinyl chloride)-methyl methacrylate-solvents have been studied by ultrasonic irradiation at 60°C. The effect of the concentrations of poly(vinyl chloride) on mechanical degradation was investigated. In addition, the effects of poly(vinyl chloride) and methyl methacrylate concentrations on mechanochemical block copolymerization were investigated. The rate equation for mechanochemical block copolymerization has been deduced, and the experimental results were in fairly good agreement with the equation. The changes in the composition of the block copolymer and homopolymers in the reaction products were followed by turbidimetric titration.

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References

  1. Schmid, G. and Rommel, O.:Z. Phys. Chem., A,185, 97 (1939).

    Google Scholar 

  2. Schmid, G. and Beuttenmüller, E.:Z. Elektrochem.,50, 209 (1944).

    Google Scholar 

  3. Jellinek, H. H. G. and White, G.:J. Polym. Sci.,6, 757 (1951);7, 21, 33 (1951).

    Google Scholar 

  4. Brett, H. W. W. and Jellinek, H. H. G.:J. Polym. Sci.,13, 441 (1954);21, 535 (1956).

    Google Scholar 

  5. Mostafa, M. A. K.:J. Polym. Sci.,27, 473 (1958);28, 519 (1958);33, 295, 311 (1958).

    Google Scholar 

  6. Eltsefon, B. S. and Berlin, A. A.:Vysokomol. Soedin.,4, 1033 (1962);5, 1562 (1963).

    Google Scholar 

  7. Chandra, S., Roy-Chowdhury, P. and Biswas, A. B.:J. Appl. Polym. Sci.,10, 1089 (1966).

    Google Scholar 

  8. Fujiwara, H., Tsunoda, M. and Goto, K.:Kobunshi Ronbunshu,32, 106 (1975).

    Google Scholar 

  9. Wu, C. B., Sheth, P. J. and Johnson, J. F.:Polymer,18, 822 (1977).

    Google Scholar 

  10. Niezette, J. and Linkens, A.:Polymer,19, 939 (1978).

    Google Scholar 

  11. Fujiwara, H., Kakiuchi, H., Kanmaki, K. and Goto, K.:Kobunshi Ronbunshu,33, 183 (1976).

    Google Scholar 

  12. Fujiwara, H., Sasaki, K., Hochi, K. and Goto, K.:Nippon Gomu Kyokaishi,52, 247 (1979).

    Google Scholar 

  13. Fujiwara, H., Kimura, K., Mori, H. and Goto, K.:Polymer J.,13, 927 (1981).

    Google Scholar 

  14. Fujiwara, H. and Goto, K.:Kobunshi Ronbunshu,41, 133 (1984).

    Google Scholar 

  15. Goto, K. and Fujiwara, H.:Kobunshi Kagaku,23, 827 (1966).

    Google Scholar 

  16. Fujiwara, H., Okazaki, K. and Goto, K.:J. Polym. Sci., Polym. Phys. Ed.,13, 953 (1975).

    Google Scholar 

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Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 16-1, Omiya 5-chome, Asaki-ku, 535, Osaka, Japan

    Hideki Fujiwara & Kunio Goto

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  1. Hideki Fujiwara
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  2. Kunio Goto
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Fujiwara, H., Goto, K. Mechanochemical block copolymerization of poly(vinyl chloride) with methyl methacrylate by ultrasonic irradiation. Polymer Bulletin 23, 27–33 (1990). https://doi.org/10.1007/BF00983960

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  • DOI: https://doi.org/10.1007/BF00983960

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