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Synthesis and preliminary characterization of rubber-polyamide multiblock copolymers

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Summary

“Hard-soft” multiblock copolymers,(AB)n type,have been prepared by incorporating rubbery segments into a polyamide 6,10 chain according to a two steps procedure. As soft segments,telechelic polybutadiene or poly(butadiene-co-acrylonitrile) oligomers have been used.The prepared copolymers have been characterized by IR spectroscopy and differential scanning calorimetry. Two different and well defined glass transitions have been observed indicating a phase segregation for the rubbery and polyamide segments.

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Authors and Affiliations

  1. Department of Chemistry, Naples University, Via Mezzocannone 4, I-80134, Naples, Italy

    Emilio Balzano, Giovanni Maglio & Rosarlo Palumbo

Authors
  1. Emilio Balzano
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  2. Giovanni Maglio
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  3. Rosarlo Palumbo
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Balzano, E., Maglio, G. & Palumbo, R. Synthesis and preliminary characterization of rubber-polyamide multiblock copolymers. Polymer Bulletin 18, 233–238 (1987). https://doi.org/10.1007/BF00255115

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  • DOI: https://doi.org/10.1007/BF00255115

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