Summary
The synthesis of novel telechelic monodispersed nonconjugated dienes from commercially available α, ω-dithiols and dienes is presented. The batch reaction produced a polydispersed. mixture separable with difficulty whereas a dropwise addition of dithiol onto an excess of α, ω-diene in the presence of peroxide led selectively and quantitatively to the addition product: diene-dithiol-diene.
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Ameduri, B., Berrada, K., Boutevin, B. et al. Synthesis of novel telechelic monodispersed nonconjugated dienes. Polymer Bulletin 28, 531–537 (1992). https://doi.org/10.1007/BF00296043
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DOI: https://doi.org/10.1007/BF00296043