Summary
This paper describes the use of certified reference materials to monitor the long-term quality of radiochemical separations. The practical limitations which determine the actual design of the quality control are discussed. The hypothesis that the high yield of the radiochemical separation will be constant with time has been checked and validated for the elements Zn, Fe, Co, Cd, Mo and to a lesser extent for W and Th using NBS SRM 1577A, BCR CRM 274 and IAEA RM A-11. This validation could not be made for the elements Cr, Au and Ag. Especially for Cr there is a serious lack of appropriate certified reference materials.
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Woittiez, J.R.W. Use of reference materials for quality control of elemental analysis by neutron activation with radiochemical separation. Fresenius J Anal Chem 338, 575–579 (1990). https://doi.org/10.1007/BF00322543
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DOI: https://doi.org/10.1007/BF00322543