Skip to main content
Log in

Dimer coverings and Kekulé structures on honeycomb lattice strips

  • Published:
Theoretica chimica acta Aims and scope Submit manuscript

Abstract

The problem of covering every site of a subsection of the honeycomb lattice with disjoint edges is considered. It is pointed out that a type of long-range order associated to such coverings can occur, so that different phases can arise as a consequence of the subsection's boundaries. These features are quantitatively investigated via a new analytic solution for a class of strips of arbitrary widths, arbitrary lengths, and arbitrary long-range-order values. Relations to work on the dimer covering problem of statistical mechanics and especially to the resonance theory of benzenoid hydrocarbons are noted.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Wheland GW (1935) J Chem Phys 3:356

    Google Scholar 

  2. Gordon M, Davison WHT (1952) J Chem Phys 20:428

    Google Scholar 

  3. Dewar MJS, Longuet-Higgins HC (1952) Proc Roy Soc (London) A214:482

    Google Scholar 

  4. Platt JR (1961) In: Flugge S (ed) Encyclopedia of physics. Springer, Berlin Göttingen Heidelberg, pp 171–240

    Google Scholar 

  5. Yen TF (1971) Theor Chim Acta 20:399

    Google Scholar 

  6. Herndon WC (1973) Tetrahedron 29:3; (1974) J Chem Ed 51:10

    Google Scholar 

  7. Randic M (1976) J Chem Soc Faraday Trans 2 72:232

    Google Scholar 

  8. Randic M (1980) Int J Quantum Chem 27:549

    Google Scholar 

  9. Cyvin SJ (1982) Monatsh Chemie 113:1127; (1983) 114:13

    Google Scholar 

  10. Trinajstic N (1983) Chemical graph theory II, chap. 2. CRC Press, Boca Raton, Florida

    Google Scholar 

  11. Fowler RH, Rushbrooke GS (1937) Trans Faraday Soc 33:1272

    Google Scholar 

  12. Read RC (1980) Fibonacci Quart 18:24

    Google Scholar 

  13. Hook JL, McQuistan RB (1983) J Math Phys 24:1859; (1984) Disc Appl Math 8:101

    Google Scholar 

  14. Phares AJ (1984) J Math Phys 25:1756

    Google Scholar 

  15. Nagle JF (1973) J Chem Phys 58:252; (1974) Proc Roy Soc (London) A337:569; (1975) Phys Rev Lett 34:1150; (1985) Phys Rev 31A:3199

    Google Scholar 

  16. Fisher ME (1984) J Stat Phys 34:667

    Google Scholar 

  17. Sachs H (1984) Combinations 4:89

    Google Scholar 

  18. Gutman I, Trinajstic N (1973) Croat Chem Acta 45:539

    Google Scholar 

  19. Cvetkovic D, Gutman I, Trinajstic N (1972) Chem Phys Lett 16:614;(1974) J Chem Phys 61:2700

    Google Scholar 

  20. Stein SE, Brown RL (1985) Carbon

  21. Fisher ME (1961) Phys Rev 124:1664

    Google Scholar 

  22. Kasteleyn PW (1963) J Math Phys 4:287

    Google Scholar 

  23. Percus JK (1969) J Math Phys 10:1881

    Google Scholar 

  24. Lieb EH (1967) J Math Phys 8:2339

    Google Scholar 

  25. Hosoya H, Yamaguchi T (1975) Tetrahedron Lett 1975:4659

    Google Scholar 

  26. Gutman I, Randic M (1979) Chem Phys 41:265

    Google Scholar 

  27. Aihara J (1977) Bull Chem Soc Jpn 50:2010

    Google Scholar 

  28. Gutman I (1977) Theor Chim Acta 45:309; (1978) Bull Chem Soc Jpn 51:2729; (1981) Math Chem 11:127

    Google Scholar 

  29. Ohkami N, Motoyama A, Yamaguchi T, Hosoya H, Gutman I (1981) Tetrahedron 37:1113

    Google Scholar 

  30. Ohkami N, Hosoya H (1983) Theor Chim Acta 64:153

    Google Scholar 

  31. Wu FY (1968) Phys Rev 168:539

    Google Scholar 

  32. Baxter RJ (1970) J Math Phys 11:784

    Google Scholar 

  33. Gutman I, Randic M (1979) Chem Phys 41:265

    Google Scholar 

  34. Elser V (1984) J Phys A17:1509

    Google Scholar 

  35. There is a (one-to-two) correspondence between Kekulé structures on the honeycomb lattice and the ground state to the antiferromagnetic Ising model on a triangular lattice. Thence the honeycomb-lattice Kekulé-structure count is given in terms of the zero-temperature entropy of this Ising model, a solution of which is given in Wannier GH (1950) Phys Rev 79:357

    Google Scholar 

  36. Harris FE, Randic M, Stolow R (unpublished work)

  37. Dzonova-Jerman-Blazic B, Trinajstic N (1982) Comput and Chem 6:121

    Google Scholar 

  38. El-Basil S, Jashari G, Knop JV, Trinajstic N (1985) Monatsh Chemie 115:1299

    Google Scholar 

  39. Ramaraj R, Balasubramanian K (1985) J Comput Chem 6:122

    Google Scholar 

  40. Elser's (Ref. [34]) cases of enumeration were also given by Yen (Ref. [5]) and Elser's maximum per-site entropy case was given by Gordon and Davison (Ref. [2]); the methods of solution were quite different though

    Google Scholar 

  41. Klein DJ (1979) Int J Quantum Chem 13S:294

    Google Scholar 

  42. Seitz WA, Klein DJ, Schmalz TG, Garcia-Bach MA (1985) Chem Phys Lett 115:139

    Google Scholar 

  43. Klein DJ, Schmalz TG, Hite GE, Metropoulos A, Seitz WA (1985) Chem Phys Lett 120:367

    Google Scholar 

  44. Klein DJ, Schmalz TG, Seitz WA, Hite GE (1985) Int J Quantum Chem 19S

  45. See, e.g., Gantmacher FR (1959) The theory of matrices, vol II, chap 13. Chelsea, New York

    Google Scholar 

  46. Pauling L (1960) The nature of the chemical bond, 3rd edn Cornell University Press, Ithaca, NY, pp. 236 ff; (1980) Acta Crystallogr B36:1898

    Google Scholar 

  47. Cruickshank DWJ, Sparks RA (1960) Proc Roy Soc (Lond) A258:270

    Google Scholar 

  48. Coulson CA (1970). In: Eyring H (ed) Physical chemistry: an advanced treatise 5. Academic Press, New York, pp 381 ff

    Google Scholar 

  49. Herndon WC (1974) J Am Chem Soc 96:7605

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Supported by The Robert A. Welch Foundation of Houston, Texas

Rights and permissions

Reprints and permissions

About this article

Cite this article

Klein, D.J., Hite, G.E., Seitz, W.A. et al. Dimer coverings and Kekulé structures on honeycomb lattice strips. Theoret. Chim. Acta 69, 409–423 (1986). https://doi.org/10.1007/BF00526700

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00526700

Key words

Navigation