Abstract
The elastic neutron scattering in polycrystalline samples of the (Ni1−x Lix)O solid solutions (x<0.1) is investigated by neutron diffraction technique. It is shown for the first time that the doping of nickel monoxide by lithium is accompanied by the formation of vacancies in the anionic sublattice, and the vacancy concentration is equal to the lithium content in the solid solution. The neutral lithium atoms are randomly arranged over sites of the cationic sublattice with possible spatial polarization of a valence electron toward an oxygen vacancy. In the composition range studied, the diamagnetic dilution of nickel monoxide by lithium turns out to be magnetically similar to the dilution with magnesium. In both cases, the Néel temperature and the mean magnetic moment per atom linearly decrease with an increase in concentration of the diamagnetic dopant.
Similar content being viewed by others
References
C. G. Shull, W. A. Strausser, and E. O. Wollan, Phys. Rev. 83, 333 (1951).
W. I. Roth, Phys. Rev. 110, 1333 (1958).
S. Koide, J. Phys. Soc. Jpn. 20(1), 123 (1965).
N. I. Mironova and U. A. Ulmanis, Radiation-Induced Defects and Iron Group Metal Ions in Oxides (Zinatne, Riga, 1988), p. 202.
T. M. Giebultovicz, J. J. Rhyne, M. S. Seehra, et al., J. Phys., Suppl. 49(12), C8–1105 (1988).
Z. Feng, V. Suresh Babu, J. Zhao, et al., J. Appl. Phys. 70, 6161 (1991).
S. Seehra, R. Kannan, and M. Ibrahim, J. Appl. Phys. 73, 5468 (1993).
A. Z. Menshikov, Ya. A. Dorofeev, A. G. Klimenko, et al., Phys. Status Solidi B 164, 275 (1991).
A. Z. Menshikov, Ya. A. Dorofeev, N. A. Mironova, et al., Solid State Commun. 98(9), 839 (1996).
A. Marini, V. Massarotti, V. Berbenni, et al., Solid State Ionics 45, 143 (1991).
V. Berbenni, V. Massarotti, D. Capsoni, et al., Solid State Ionics 48, 101 (1991).
J. B. Goodenough, D. G. Wickhow, and W. J. Croft, J. Phys. Chem. Solids 5, 107 (1958).
W. Li, J. N. Reimers, and J. R. Dahn, Phys. Rev. B: Condens. Matter 46(6), 3236 (1992).
R. Stoyanova, E. Zhecheva, and S. Angelov, Solid State Tech. 59, 17 (1993).
F. Kern and N. Perakis, C. R. Acad. Sci. B 279(6), 143 (1974).
J. Rodríguez-Carvajal, Physica B (Amsterdam) 192, 55 (1993).
A. A. Arkhipov, Izv. AN Latv. SSR, Ser. Fiz. Tekh. Nauk 3, 13 (1986).
J. P. Kemp, P. A. Cox, and J. W. Hodby, J. Phys.: Condens. Matter, No. 2, 6699 (1990).
Author information
Authors and Affiliations
Additional information
__________
Translated from Fizika Tverdogo Tela, Vol. 42, No. 2, 2000, pp. 307–312.
Original Russian Text Copyright © 2000 by Men’shikov, Dorofeev, Teplykh, Gizhevski\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \), Mironova.
Rights and permissions
About this article
Cite this article
Men’shikov, A.Z., Dorofeev, Y.A., Teplykh, A.E. et al. Neutron diffraction investigation of structural and magnetic states of lithium-doped antiferromagnet NiO. Phys. Solid State 42, 315–320 (2000). https://doi.org/10.1134/1.1131204
Received:
Issue Date:
DOI: https://doi.org/10.1134/1.1131204