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Crystal and molecular structure of complex compound [Fe3O(CH3COO)6(H2O)3]2[ZnCl4] ⋅ 2H2O

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Abstract

The X-ray crystal structure of trinuclear iron acetate [Fe3O(CH3COO)6(H2O)3]2 [ZnCl4] ⋅ 2H2O was determined. The crystal has a ionic structure. It is monoclinic, a = 25.363(7), b = 14.533(4), c = 15.692(4) Å, β = 103.11(2)°, space group C2/c, and R = 0.0685. The structure of the cationic complex [Fe3O(CH3COO)6(H2O)3]+ is typical of trinuclear iron(III) compounds containing a μ3-O bridge: the iron atoms are situated at the vertices of an almost equilateral triangle with the O atom at the center. Each Fe atom is coordinated by four O atoms of bridging carboxy groups, the μ3-bridging O atom, and the water molecule in the trans position to the latter O atom. Mössbauer spectroscopy evidence indicates the high-spin state (S = 5/2) of the iron(III) ions.

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Authors and Affiliations

  1. Institute of Applied Physics, Academy of Sciences of Moldova, Academiei 5, Chisinau, 20-28, Moldova

    S. G. Shova, I. G. Cadelnic & Ya. A. Simonov

  2. Mickiewicz University, Grunwaldzka 6, Poznan, 60-780, Poland

    M. Gdaniec

  3. Institute of Chemistry, Academy of Sciences of Moldova, Academiei 3, Chisinau, 20-28, Moldova

    T. C. Jovmir, I. I. Bulhac & C. I. Turta

  4. National Institute of Physics and Technology of Materials, P.O. Box MG-7, Bucharest, 76900, Romania

    G. Filoti

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  1. S. G. Shova
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  2. I. G. Cadelnic
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  3. M. Gdaniec
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  5. T. C. Jovmir
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  6. G. Filoti
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  7. I. I. Bulhac
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  8. C. I. Turta
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__________

Translated from Kristallografiya, Vol. 45, No. 3, 2000, pp. 458–464.

Original Russian Text Copyright © 2000 by Shova, Cadelnic, Gdaniec, Simonov, Jovmir, Filoti, Bulhac, Turta.

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Shova, S.G., Cadelnic, I.G., Gdaniec, M. et al. Crystal and molecular structure of complex compound [Fe3O(CH3COO)6(H2O)3]2[ZnCl4] ⋅ 2H2O. Crystallogr. Rep. 45, 416–421 (2000). https://doi.org/10.1134/1.171209

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  • DOI: https://doi.org/10.1134/1.171209

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