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Formation of C1–C5 Hydrocarbons from CCl4 in the Presence of Carbon-Supported Palladium Catalysts

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Abstract

Along with hydrodechlorination, the formation of C1 and higher hydrocarbons takes place in a flow system in the presence of catalysts containing 0.5–5.0% Pd supported on a Sibunit carbon carrier at 150–230°C. In the entire range of conditions examined, the reaction products are primarily methane, C2–C4 hydrocarbon fractions, and C5 traces. The catalysts are stable in operation, and a high conversion of CCl4 was retained for a long time interval. The nonselective formation of linear and branched hydrocarbons is indicative of a radical mechanism of the process.

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Article Open access 02 December 2021

Baoxin Zhang, Dilver Peña Fuentes & Armin Börner

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Authors and Affiliations

  1. Moscow State University, Moscow, 119899, Russia

    E. S. Lokteva, E. V. Golubina & V. V. Lunin

  2. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. I. Simagina & I. V. Stoyanova

Authors
  1. E. S. Lokteva
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  2. V. I. Simagina
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  3. E. V. Golubina
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  4. I. V. Stoyanova
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  5. V. V. Lunin
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Lokteva, E.S., Simagina, V.I., Golubina, E.V. et al. Formation of C1–C5 Hydrocarbons from CCl4 in the Presence of Carbon-Supported Palladium Catalysts. Kinetics and Catalysis 41, 776–781 (2000). https://doi.org/10.1023/A:1026621102928

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  • DOI: https://doi.org/10.1023/A:1026621102928

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