Abstract
The chemisorption of hexamethyldisilazane on the surface of a highly dispersed graphite has been studied. It was shown that with increase in the reaction temperature, the amount of the grafted trimethysilyl groups increases. The characteristic features of the formation of the trimethylsilyl coating have been discussed on the basis of the data on the thermodesorption of water, carbon oxides and methane from graphite surfaces with mass-spectrometric monitoring.
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A. J. Groszek and R. E. Witheridge, ASLE Trans.14, No. 4, 254–266 (1971).
“Goldsworthy 82.” Update-Composite Manufacturing Technology. Progr. Sci and Eng. Compose: Proc. of the 4th Intern. Conf. ICCM-IV, Tokyo, Oct. 25–28 (1982), Vol. 2, Tokyo (1982), pp. 1835–1842.
Yu. A. Zarif'yants, V. F. Kiselev, and G. G. Fedorov, Zh. Fiz. Khim.,36, No. 3, 1185–1186 (1961).
N. G. Vasil'ev, L. V. Golovko, and F. D. Ovcharenko, Kolloidn. Zh., No. 5, 842–846 (1976).
C. P. Boehm, Catalysis. Stereochemistry and Mechanisms of Organic Reactions [Russian translation], Mir, Moscow (1968),
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Deceased.
Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 28, No. 2, pp. 184–186, March–April, 1992.
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Golovko, L.V., Povazhnyi, V.A., Nazarenko, V.A. et al. Methylsilylation of highly dispersed graphite surfaces. Theor Exp Chem 28, 160–162 (1993). https://doi.org/10.1007/BF00573931
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DOI: https://doi.org/10.1007/BF00573931