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Mössbauer spectroscopy of liquid SnCl4 solutions trapped in a rigid microemulsion

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Abstract

A rigid microemulsion was prepared containing submicroscopic droplets of liquid aqueous tin tetrachloride solution. Recoillessγ-ray resonance absorption (the Mössbauer effect] was achieved in this system, indicating that the organic dispersion medium of the microemulsion behaved as a carrier, enhancing the Debye-Waller factor for the quasiliquid phase of the system. The Mössbauer spectra reflected the presence of two types of tin(IV) in the cavities of the microemulsion: SnCl4 species situated in the bulk solution and on the cavity wall, respectively.

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Authors and Affiliations

  1. Department of Inorganic and Analytical Chemistry, A. József University, P.O. Box 440, H-6701, Szeged, Hungary

    K. Burger

  2. Laboratory of Nuclear Chemistry, L. Eötvös University, Budapest, Hungary

    A. Vértes

  3. Department of Colloid Chemistry, A József University, Szeged, Hungary

    I. Dékány

  4. Department of Inorganic and Analytical Chemistry, A. József University, P.O. Box 440, H-6701, Szeged, Hungary

    Zs. Nemes-Vetéssy

Authors
  1. K. Burger
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  2. A. Vértes
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  3. I. Dékány
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  4. Zs. Nemes-Vetéssy
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Burger, K., Vértes, A., Dékány, I. et al. Mössbauer spectroscopy of liquid SnCl4 solutions trapped in a rigid microemulsion. Struct Chem 2, (69)277–(72)280 (1991). https://doi.org/10.1007/BF00672223

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  • DOI: https://doi.org/10.1007/BF00672223

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