Skip to main content
Log in

Activity coefficients for NaBr in ethanol-water mixtures at 25°C

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Activity coefficients for NaBr in ethanol-water mixtures with 0, 20, 40, 60, 70, 80, 90 and 99.9 weight% of ethanol have been determined at 25°C from the emf measurements of the galvanic cells

$$Na - glass/NaBr(m),H_2 O(100 - Y),EtOH(Y),AgBr_{(S)} /Ag$$

The results obtained were analyzed by using the Pitzer equation. Those for the mixtures with ethanol content higher than 60 wt% were also analyzed by using a chemical model and their ion pair formation constants, K 0A , determined and examined. The results were compared with those for NaCl reported in a previous paper.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. A. Esteso, O. M. González-Díaz, F. F. Hernández-Luis, and L. Fernández-Mérida,J. Solution Chem. 18, 277 (1989).

    Google Scholar 

  2. G. J. Janz,Reference Electrodes. Theory and Practice, D. J. G. Ives and G. J. Janz, eds., (Academic Press, New York, 1961), p. 209.

    Google Scholar 

  3. R. N. Roy, J. J. Gibbons, R. Snelling, J. Moeller, and T. White,J. Phys. Chem. 81, 391 (1977).

    Google Scholar 

  4. M. A. Esteso, L. Fernández-Mérida, F. Hernández-Luis, and O. M. González-Díaz,J. Electroanal. Chem. 255, 71 (1988).

    Google Scholar 

  5. A. J. Zielen,J. Phys. Chem. 67, 1474 (1963).

    Google Scholar 

  6. H. S. Harned and B. B. Owen,Physical Chemistry of Electrolyte Solutions, 3rd edn. (Reinhold, New York, 1958), pp. 166, 683.

    Google Scholar 

  7. R. N. Roy, R. A. Robinson, and R. G. Bates,J. Chem. Thermodyn. 5, 559 (1973).

    Google Scholar 

  8. International Critical Tables of Numerical Data. Physics, Chemistry and Technology, Vol. III, E. W. Washburn, ed., (McGraw-Hill, New York, 1928), p. 77.

    Google Scholar 

  9. H. O. Spivey and T. Shedlovsky,J. Phys. Chem. 71, 2165 (1967).

    Google Scholar 

  10. M. A. Esteso, D. M. Grandoso, and M. M. Lemus,J. Chem. Eng. Data 31, 215 (1986).

    Google Scholar 

  11. A. W. Garner and E. Glueckauf,Proc. Roy. Soc. (London) A313, 131 (1969).

    Google Scholar 

  12. C.-F. Pan,Can. J. Chem. 54, 9 (1976);58, 1386 (1980).

    Google Scholar 

  13. E. A. Guggenheim and R. H. Stokes,Equilibrium Properties of Aqueous Electrolyte Solutions, 1st ed. (Pergamon, New York, 1969), p. 125.

    Google Scholar 

  14. Y. Marcus,Ion Solvation, (Wiley, Chichester, 1985), p. 80.

    Google Scholar 

  15. K. S. Pitzer,J. Phys. Chem. 77, 268 (1973).

    Google Scholar 

  16. D. S. P. Koh, K. H. Khoo, and C.-Y. Chan,J. Solution Chem. 14, 635 (1985).

    Google Scholar 

  17. K. S. Pitzer,J. Chem. Soc. Faraday Trans. II 68, 101 (1972).

    Google Scholar 

  18. R. A. Robinson and R. H. Stokes,Electrolyte Solutions (Butterworths, London, 1959), p. 336.

    Google Scholar 

  19. R. M. Fuoss and K.-L. Hsia,Proc. Nat. Acad. Sci. 57, 1550 (1967).

    Google Scholar 

  20. Y. Marcus, N. Ben-Zwi, and I. Shiloh,J. Solution Chem. 5, 87 (1976).

    Google Scholar 

  21. J. Ananthaswamy and G. Atkinson,J. Chem. Eng. Data 29, 81 (1984).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

González-Díaz, O.M., Fernández-Mérida, L., Hernández-Luis, F. et al. Activity coefficients for NaBr in ethanol-water mixtures at 25°C. J Solution Chem 24, 551–563 (1995). https://doi.org/10.1007/BF00973206

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00973206

Key words

Navigation