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Synthesis, characterization, peripheral studies, and structural analysis of E-4-(N-methylanilino)-3-pentene-2-one, C12H15NO

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Abstract

Crystallographic structural refinement of E-4-(N-methylanilino)-3-pentene-2-one (I) has been carried out by means of three-dimensional single-crystal X-ray diffractometry. The title compound crystallizes in space group C2 (No. 5,Z = 4). The lattice constants are a = 21.543(4), b = 6.433(1), c = 8.019(2) Å, and β = 97.82(3)°. Characterizations include physical property determinations and spectrometric identifications employing IR, 1H and 13C NMR, and X-ray powder analyses. The molecules in the crystal lattice are held together by van der Waals forces. Selected bond distances and angles are presented and discussed as well as synthesis and peripheral studies.

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Authors and Affiliations

  1. Department of Chemistry, Baylor University, Waco, Texas, 76798-7348

    Donald F. Mullica, J. Matt Farmer & Jason A. Kautz

  2. Department of Chemistry, University of Mary Hardin-Baylor, Belton, Texas, 76513-2599

    Dennis R. Dillin, Darrell G. Watson & Michael Angel

Authors
  1. Donald F. Mullica
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  2. Dennis R. Dillin
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  3. Darrell G. Watson
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  4. Michael Angel
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  5. J. Matt Farmer
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  6. Jason A. Kautz
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Mullica, D.F., Dillin, D.R., Watson, D.G. et al. Synthesis, characterization, peripheral studies, and structural analysis of E-4-(N-methylanilino)-3-pentene-2-one, C12H15NO. Journal of Chemical Crystallography 28, 899–903 (1998). https://doi.org/10.1023/A:1022802619976

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