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Metal complexes of chiral pyridine ligands. X-ray structure of nitratobis {2-(2S)-2-pyrrolidinyl]pyridine} copper (II) nitrate

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Abstract

Cobalt(II), nickel(II), and copper(II) complexes of 2-[(2S)-2-pyrrolidinyllpyridine (L) have been synthesized and characterized. The crystal structure of the complex [Cu(L)2(NO3)]NO3 has been determined by X-ray diffraction. Crystals are monoclinic, space groupP2+, witha=10.766(3).b=7.525(2),c=13.447(4) Å. β=104.64(2)°. and Z=2. The structure consists of [Cu(L)2(NO3)]+ cations and NO t-3 anions. The copper atom has a distorted trigonal bipyramidal coordination geometry with the two pyrrolidine nitrogens and one nitrate oxygen occupying the equatorial positions and the two pyridine nitrogens at the apices. The crystalline cohesion is ensured by a network of hydrogen bonds involving the pyrrolidine groups as donors and both coordinate and uncoordinate nitrates as acceptors.

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Authors and Affiliations

  1. Dipartimento di Chimica Generale ed Inorganica. Chimica Analitica, Chimica Fisica, Università di Parma, Viale delle Scienze, 43100, Parma, Italy

    Alessia Bacchi, Corrado Pelizzi & Giancarlo Pelizzi

  2. Dipartimento di Chimica, Università di Sassari, Via Vienna 2, 07100, Sassari, Italy

    Giorgio Chelucci

  3. Istituto di Chimica Biologica, Università di Sassari, Via Muroni 23, 07100, Sassari, Italy

    Manlio Grandino, Giovannina Minardi & Costantino Solinas

Authors
  1. Alessia Bacchi
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  2. Giorgio Chelucci
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  3. Manlio Grandino
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  4. Giovannina Minardi
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  5. Corrado Pelizzi
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  6. Giancarlo Pelizzi
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  7. Costantino Solinas
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Bacchi, A., Chelucci, G., Grandino, M. et al. Metal complexes of chiral pyridine ligands. X-ray structure of nitratobis {2-(2S)-2-pyrrolidinyl]pyridine} copper (II) nitrate. J Chem Crystallogr 24, 659–663 (1994). https://doi.org/10.1007/BF01668226

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  • DOI: https://doi.org/10.1007/BF01668226

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