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Crystal structure of phenyl bis(O-isopropylxanthato s,s′)arsenic(III)

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Abstract

The crystal structure of the title compound PhAs(S2COPri)2 has been determined by single crystal X-ray diffraction and refined by full matrix least squares analysis with anisotropic temperature factors. The crystal is monoclinic, space groupP21/c,a=8.889(6),b=16.174(19),c=13.506(14) Å,β=102.02(7)°,V=1899.2 Å3,Z=4,D c=1.478 g cm−3, monochromated Mo-Kα radiation, λ=0.71069 Å,μ=22.07 cm−1.

The geometry around the arsenic atom is square pyramidal. Each ligand is bonded to an arsenic atom through two unequal As-S bonds measuring 2.298 and 3.041 Å. The apical position is occupied by a phenyl group and a lone pair of electrons is presenttrans to the phenyl group.

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References

  • Bally, R. (1967)Acta Crystallogr. 2, 23.

    Google Scholar 

  • Carrai, C., and Gottardi, G. (1960)Z. Kristallogr. 113, 373.

    Google Scholar 

  • Enraf Nonius Structure Determination Package Enraf Nonius Delft Holland (1983).

  • Frenz, B. A. (1978) InComputing in crystallography, H. Schenk, R. Olthof-Hazekamp, H. Van Koningsveld, and G. C. Bassi (eds.), (Delft University Press, Delft The Netherlands), pp. 44–71.

    Google Scholar 

  • Friedman, H. G., Choppin, Jr., G. R., and Fruerbacher, D. G. (1964)J. Chem. Ed. 354.

  • Graziani, R., Bombieri, G., Forsellini, E., Furlan, P., Veruzo, V., and Tagliavini, G. (1977)J. Organomet. Chem. 125, 43.

    Google Scholar 

  • Gupta, R. K., Rai, A. K., and Mehrotra, R. C. (1984)Polyhedron 3, 721.

    Google Scholar 

  • Gupta, R. K., Rai, A. K., Mehrotra, R. C., Jain, V. K., Hoskins, B. F., and Tiekink, E. R. T. (1985)Inorg. Chem. 24, 3280.

    Google Scholar 

  • Hoskins, B. F., Piko, P. M., Tiekink, E. R. T., and Winter, G. (1984)Inorg. Chim. Acta 84, L13.

    Google Scholar 

  • Hoskins, B. F., Tiekink, E. R. T., and Winter, G. (1985)Inorg. Chim. Acta 99, 177.

    Google Scholar 

  • International Tables for X-ray Crystallography (1968) (Kynoch Press Birmingham, England).

  • Ito, T., and Hishino, H. (1983)Acta Crystallogr. C 39, 448.

    Google Scholar 

  • Walker, N., and Stuart, D. (1983)Acta Crystallogr. A 39, 159.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University of Rajasthan, 302 004, Jaipur, India

    R. Karra, Y. P. Singh, R. Bohra & A. K. Rai

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  1. R. Karra
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  2. Y. P. Singh
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  3. R. Bohra
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  4. A. K. Rai
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Karra, R., Singh, Y.P., Bohra, R. et al. Crystal structure of phenyl bis(O-isopropylxanthato s,s′)arsenic(III). Journal of Crystallographic and Spectroscopic Research 22, 721–724 (1992). https://doi.org/10.1007/BF01160992

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  • DOI: https://doi.org/10.1007/BF01160992

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