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Study on the crystal and molecular structure of triphenyl tin methacrylate: (C6H5)3SnOCOCCH2CH3

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Abstract

The crystal and molecular structure of (C6H5)3SnOCOCCH2CH3 has been determined by a single crystal X-ray diffraction study. The crystal is monoclinic with space group P21/c,a=11.902(3),b=10.104(4),c=16.721(2) Å,β=97.56(1)°,V=1930.4 Å3,Z=4 andD c =1.495 g/ cm3,F(0,0,0)=872,λ(CuKα)=1.5418 Å. The structure was solved by the heavy-atom method and refined by full-matrix least-squares procedures to anR factor of 0.060 based on 2157 independent reflections. The results showed that the Sn-O bond distance is 2.064(4) Å. The average Sn-C bond distance is 2.126 Å. There is a weak coordination through the O of the CO group of the methacrylate residue (Sn-O(2) 2.774(5) Å) except for four normal coordinations. The coordination number at the Sn4+ is 5.

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Authors and Affiliations

  1. Structure Research Laboratory, University of Science and Technology of China Academia Sinica, Hefei, Anhui, China

    Guien Zhou

  2. Department of Applied Chemistry, University of Science and Technology of China, Hefei, Anhui, China

    Yu Deng, Zhewen Han & Pingping Wu

Authors
  1. Lei Shi
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  2. Guien Zhou
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  3. Yu Deng
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  4. Zhewen Han
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  5. Pingping Wu
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Shi, L., Zhou, G., Deng, Y. et al. Study on the crystal and molecular structure of triphenyl tin methacrylate: (C6H5)3SnOCOCCH2CH3 . Journal of Crystallographic and Spectroscopic Research 21, 277–280 (1991). https://doi.org/10.1007/BF01156078

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  • DOI: https://doi.org/10.1007/BF01156078

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