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The structure of 5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octane

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Abstract

From the1H,13C, and119Sn NMR spectra at different temperatures, it is concluded that the 5-alkyl-5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octanes dimerize in nonpolar solvents. The barrier for dimerization is lower (ΔG ‡=40 kJ/mol) than the barrier for simultaneous dissociation-inversion (ΔG ‡=70 kJ/mol). The dimers studied are sterically uniform.

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References

  • Donaldson, J. (1967)Prog. Inorg. Chem. 8, 287.

    Google Scholar 

  • Gsell, R., and Zeldin, M. (1976)J. Inorg. Nucl. Chem. 37, 1133.

    Google Scholar 

  • Hsu, C. C., and Geanangel, R. A. (1980)Inorg. Chem. 19, 110.

    Google Scholar 

  • Mügge, C., Jurkschat, K., Zschunke, A., and Tzschach, A. (1979)J. Organomet. Chem. 164, 135.

    Google Scholar 

  • Stevenson, P. E., Bhat, G., Buschweller, C. H., and Anderson, W. G. (1974)J. Am. Chem. Soc. 96, 1067.

    Google Scholar 

  • Tzschach, A., and Uhlig, W. (1981)Z. Anorg. Allgem. Chem. 475 251.

    Google Scholar 

  • Tzschach, A., Jurkschat, K., Zschunke, A., and Mügge, C. (1980)J. Organomet. Chem. 193, 299.

    Google Scholar 

  • Zeldin, M., and Gsell, R. (1976)Synh. React. Inorg. Met. Org. Chem. 6, 11.

    Google Scholar 

  • Zeldin, M., Gsell, R. (1978)J. Inorg. Nucl. Chem. 40, (1978).

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Authors and Affiliations

  1. Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR

    A. Zschunke, C. Mügge, M. Scheer, K. Jurkschat & A. Tzschach

Authors
  1. A. Zschunke
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  2. C. Mügge
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  3. M. Scheer
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  4. K. Jurkschat
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  5. A. Tzschach
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Zschunke, A., Mügge, C., Scheer, M. et al. The structure of 5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octane. Journal of Crystallographic and Spectroscopic Research 13, 201–210 (1983). https://doi.org/10.1007/BF01161514

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  • DOI: https://doi.org/10.1007/BF01161514

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