Abstract
Hydrogenation of adsorbed ethene over ZrO2 at low temperature was observed by in situ infrared transmission spectroscopy. It was found that di-hydrogen was directly activated on the site where ethene was already adsorbed, which was confirmed by the comparison of adsorbed species produced during the reaction and adsorbed ethane species.
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References
H.L. Little, in:Infrared Spectra of Adsorbed Species (Academic Press, London, 1966).
R.P. Eischens and W.A. Pliskin, Adv. Catal. 10 (1958) 1.
J. Horiuti and K. Miyahara, in:Hydrogenation of Ethylene on Metallic Catalysts, NSRDS-NBS No. 13 (1968).
J. Horiuti and M. Polanyi, Trans. Faraday Soc. 30 (1934) 1164.
A. Farkas and L. Farkas, J. Am. Chem. Soc. 66 (1938) 22.
R.J. Koestner, M.A. Van Hove and G.A. Somorjai, J. Phys. Chem. 87 (1983) 203; and references therein.
G.A. Somorjai, M.A. Van Hove and B.E. Bent, J. Phys. Chem. 92 (1988) 973; and references therein.
F. Zaera and G.A. Somorjai, J. Am. Chem. Soc. 106 (1984) 2288.
D. Godbey, F. Zaera, R. Yates and G.A. Somorjai, Surf. Sci. 167 (1986) 150.
T.P. Beebe, Jr. and J.T. Yates, Jr., J. Am. Chem. Soc. 108 (1986) 663.
A.B. Anderson and S.J. Choe, J. Phys. Chem. 93 (1989) 6145.
R.L. Burwell, Jr., A.B. Littlewood, M. Cadew, G. Pass and C.T.H. Stoddart, J. Am. Chem. Soc. 82 (1960) 6272.
G. Pass, A.B. Littlewood and R.L. Burwell, Jr., J. Am. Chem. Soc. 82 (1960) 6281.
C.T.H. Stoddart, G. Pass and R.L. Burwell, Jr., J. Am. Chem. Soc. 82 (1960) 6284.
A.B. Littlewood and R.L. Burwell, Jr., J. Am. Chem. Soc. 82 (1960) 6287.
M. Cardew and R.L. Burwell, Jr., J. Am. Chem. Soc. 82 (1960) 6289.
J.L. Carter, P.J. Lucchesi, J.H. Sinfelt and D.J.C. Yates,Proc. 3rd Intern. Congr. Catal (North-Holland, Amsterdam, 1964) Vol. 1, p. 644.
J.H. Sinfelt, J. Phys. Chem. 68 (1964) 232.
Y. Amenomiya, J.H.B. Chenier and R.J. Cvetanovic, J. Catal. 9 (1967) 28.
W.C. Conner, R.A. Innes and R.J. Kokes, J. Am. Chem. Soc. 90 (1968) 6858.
A.L. Dent and R.J. Kokes, J. Phys. Chem. 73 (1969) 3772.
A.L. Dent and R.J. Kokes, J. Phys. Chem. 73 (1969) 3781.
A.L. Dent and R.J. Kokes, J. Phys. Chem. 73 (1969) 2436.
A.L. Dent and R.J. Kokes, J. Am. Chem. Soc. 91 (1969) 7207.
A.L. Dent and R.J. Kokes, J. Phys. Chem. 74 (1970) 3653.
J. Kondo, K. Domen, K. Maruya and T. Onishi, J. Chem. Soc., Faraday Trans. 86 (1990) 397.
J. Kondo, K. Domen, K. Maruya and T. Onihsi, J. Chem. Soc., Faraday Trans. 86 (1990) 3021.
J. Kondo, K. Domen, K. Maruya and T. Onishi, J. Chem. Soc., Faraday Trans. 86 (1990) 3665.
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Domen, K., Kondo, J., Maruya, K. et al. Infrared studies of ethene hydrogenation over ZrO2 . Catal Lett 12, 127–137 (1992). https://doi.org/10.1007/BF00767195
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DOI: https://doi.org/10.1007/BF00767195