Skip to main content
SpringerLink
Log in

Co2+ and Mn2+ ion locations in doped CsCdCl3

  • Published:
Il Nuovo Cimento D

Summary

Substitutional Co2+ and Mn2+ ions at the two different Cd sites in the compound CsCdCl3 have been studied by using electron paramagnetic resonance. The preferential occupation, Co2+ in the CdII site, Mn2+ in the CdI site, is discussed in terms of crystallochemical symmetry arguments.

Riassunto

Gli ioni di sostituzione Co2+ e Mn2+ in due diverse posizioni nel Cd nel composto CsCdCl3 sono state studiati usando la risonanza paramagnetica elettronica. L'occupazione preferenziale, Co2+ nel sito CdII, Mn2+ nel sito CdI, è discussa in termini di argomenti di simmetria della chimica dei cristalli.

Резюме

Используя электронный парамагнитный резонанс, в соединении CsCdCl3 исследуются местоположения ионов замещения Co2+ и Mn2+ в двух различных положениях Cd. В терминах кристалло-химической симметрии обсуждается предпочтительное расположение Co2+ в положении CdII и Mn2+ в положении CdI.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. S. Siegel andE. Gebert:Acta Crystallogr.,17, 790 (1964).

    Article  Google Scholar 

  2. J. R. Chang, G. L. Mc Pherson andJ. L. Atwood:Inorg. Chem.,14, 3079 (1975).

    Article  Google Scholar 

  3. S. O. Graham andR. L. White:Phys. Rev. B,10, 4505 (1974).

    Article  ADS  Google Scholar 

  4. G. L. Mc Pherson andJ. R. Chang:J. Magn. Reson.,14, 310 (1974).

    Google Scholar 

  5. A. Edgar:J. Phys. C,9, 4303 (1976).

    Article  ADS  Google Scholar 

  6. A. Abragam andB. Bleaney:Electron Paramagnetic Resonance of Transition Ions (Oxford, 1970), p. 446.

  7. A. Abragam andB. Bleaney:Electron Paramagnetic Resonance of Transition Ions (Oxford, 1970), p. 847.

  8. K. Adachi:J. Phys. Soc. Jpn.,50 3904 (1981).

    Article  ADS  Google Scholar 

  9. J. R. Longo andJ. A. Kafalas:J. Solid State. Chem.,3, 429 (1971).

    Article  ADS  Google Scholar 

  10. L. Pauling:The Nature of the Chemical Bond (Ithaca, N. Y., 1960).

  11. A. Abragam andM. H. L. Pryce:Proc. R. Soc. London, Ser. A,206, 173 (1951).

    Article  MATH  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Spectroscopie et d'Optique du Corps Solide Associé au C.N.R.S.No. 232, Université Louis Pasteur 5, rue de l'Université, 67000, Strasbourg, France

    M. Bensekrane, A. Goltzene, B. Meyer & C. Schwab

  2. Centre for Materials Research, Stanford University, 94305, Stanford, Cal.

    D. Elwell & R. S. Feigelson

Authors
  1. M. Bensekrane
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Goltzene
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. Meyer
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. C. Schwab
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. Elwell
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. R. S. Feigelson
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bensekrane, M., Goltzene, A., Meyer, B. et al. Co2+ and Mn2+ ion locations in doped CsCdCl3 . Il Nuovo Cimento D 2, 1964–1970 (1983). https://doi.org/10.1007/BF02457895

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02457895

PACS. 76.30

Search

Navigation