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Synthesis of cationic carbonyl complexes of manganese(I) with bidentate ligands

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Summary

Bidentate ligands can readily replace acetone in thefac-[Mn(CO)3(chel)(OCMe2)]+ complexes or the perchlorate group fromfac-[Mn(CO)3(chel)(OClO3)] yieldingfac-[Mn(CO)3(chel)(L-L)]+ or [{fac-Mn(CO)3(chel)}2(L-L)]2+ [chel = 1,10-phenanthroline (phen), 2,2′-bipyridine (bipy), 1,2-bis(diphenylphosphine)ethane (dpe); L-L = bis(diphenylphosphine)methane (dpm), dpe, 1,4-bis(diphenylphosphine)butane (dpb), succinonitrile (suc), and glutaronitrile (glu)]. Some of these mononuclear complexes are precursors for binuclear complexes which are linked by bridging phosphines or nitriles.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, University of Valladolid, Valladolid, Spain

    M. Pilar Gamasa, Mariano Laguna, Daniel Miguel & Víctor Riera

  2. Department of Inorganic Chemistry, University of Zaragoza, Spain

    Mariano Laguna

Authors
  1. M. Pilar Gamasa
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  2. Mariano Laguna
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  3. Daniel Miguel
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  4. Víctor Riera
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Gamasa, M.P., Laguna, M., Miguel, D. et al. Synthesis of cationic carbonyl complexes of manganese(I) with bidentate ligands. Transition Met Chem 6, 374–376 (1981). https://doi.org/10.1007/BF00623661

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  • DOI: https://doi.org/10.1007/BF00623661

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