Summary
The structure of PtCl(CF3)(cis-Ph2PCH=CHPPh2), has been determined from three-dimensional x-ray data. The complex crystallizes in the monoclinic system, space group C 52h -P21/n witha=19.781(6),b=15.024(5),c=8.547(3) Å,β=93.2(1)° andZ=4. Least-squares refinement has led to a value of the conventional R index (on F) of 0.055 for the 3199 independent reflections having I⩾2.5σ (I). The complex is a typical square-planar PtII complex with structural parameters: Pt-P, 2.275(4) (a)trans to CF3 and 2.236(4) (b)trans to Cl, Pt-Cl, 2.346(4), Pt-C(F), 2.188(8), C(A) = C(B), 1.38(2) Å; Cl-Pt-P(1), 91.1(1), P(1)-Pt-P(2), 86.2(1)°.
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References
M. L. H. Green, G. E. Coates, M. L. Green and K. WadeOrganometallic Compounds, 1968, 3rd Edit., Vol. 2, Methuen, London.
P. J. Davidson, M. F. Lappert and R. Pearce,Chem. Rev., 76, 219 (1976).
A. Wojcicki,Adv. Organometal. Chem., 11, 87 (1973).
M. A. Bennett, G. B. Robertson, P. O. Whimp and T. Yoshick,J. Am. Chem. Soc., 95, 3028 (1973).
M. A. Cairns, K. R. Dixon and M. A. R. Smith,J. Organometal. Chem., 135, C33 (1977).
R. Ros, R. A. Michelin, U. Belluco, G. Zanotti, A. Del Pra and G. Bombieri,Inorg. Chim. Acta, 29, L 187 (1978).
R. Ros, R. A. Michelin, G. Carturan and U. Belluco,J. Organometal. Chem., 133, 213 (1977).
R. Ros, R. A. Michelin, R. Bataillard and R. Roulet,J. Organometal. Chem., 161, 75 (1978).
T. G. Appleton, M. H. Chisholm, H. C. Clark and L. E. Manzer,Inorg. Chem., 11, 1786 (1972).
H. C. Clark and L. E. Manzer,J. Organometal Chem., 59, 411 (1973).
T. G. Appleton and M. A. Bennett,Inorg. Chem., 17, 738 (1978).
R. A. Michelin, U. Belluco and R. Ros,Inorg. Chim. Acta, 24, L33 (1977).
L. Manojlovic-Muir, K. W. Muir, T. Solomon, D. W. Meek and J. L. Peterson,J. Organometal. Chem., 146, C26 (1978).
D. R. Russell and P. A. Tucker,J. Chem. Soc. Dalton Trans., 2222 (1975).
J. Howard and P. Woodward,J. Chem. Soc. Dalton Trans., 1840 (1973).
A. C. T. North, D. C. Phillips and F. S. Mathews,Acta Crystallogr., A24, 351 (1968).
International Tables for X-ray Crystallography, Vol. IV, 2nd Edit, 99, Kynoch Press, Birmingham (1974).
International Tables for X-ray Crystallography, Vol. IV, 2nd Edit, 149, Kynoch Press, Birmingham (1974).
R. Eisenberg and J. A. Ibers,Inorg. Chem., 4, 773 (1965).
G. Sheldrick, “SHELX 76” System of Computing Programs. University of Cambridge (1976).
R. Ugo, F. Conti, S. Cenini, R. Mason and G. B. Robertson,Chem. Comm., 1498 (1968).
F. Cariati, R. Mason, G. B. Robertson and R. Ugo,Chem. Comm., 408 (1967).
R. Mason and D. W. Meek,Angew. Chem. Internat. Edit. Engl., 17, 183 (1978).
R. M. Kirchner, R. G. Little, K. D. Tan and D. W. Meek,J. Organometal. Chem., 149, C15 (1978).
D. Schwarzenbach, A. Pinkerton, G. Chapuis, J. Wenger, R. Ros and R. Roulet,Inorg. Chim. Acta, 25, 255 (1977).
P. R. Wells,Progr. Phys. Org. Chem., 6, 111 (1968).
T. G. Appleton, H. C. Clark and L. E. Manzer,Coord. Chem. Rev., 10, 335 (1973).
R. Ros, R. A. Michelin, T. Boschi and R. Roulet, unpublished work.
J. A. Kaduk and J. A. Ibers,J. Organometal Chem., 139, 199 (1977).
P. B. Hitchcock, B. Jacobson and A. Pidcock,J. Chem. Soc. Dalton Trans., 2043 (1977).
M. R. Snow and J. A. Ibers,Inorg. Chem., 12, 224 (1973).
M. A. Bennett, K. C. Ho, G. B. Robertson and P. O. Whimp, unpublished results quoted in G. B. Robertson and P. O. Whimp,Inorg. Chem., 13, 2082 (1974).
L. Pauling,The Nature of the Chemical Bond. Cornell University Press, Ithaca, N. Y., 1960, 3rd Edit., p. 139.
S. J. La Placa and J. A. Ibers,Inorg. Chem., 4, 778 (1965).
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Del Pra, A., Zanotti, G., Piazzesi, A. et al. The crystal and molecular structure of PtCl(CF3)(cis-Ph2PCH=CHPPh2). Transition Met Chem 4, 381–384 (1979). https://doi.org/10.1007/BF00623983
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DOI: https://doi.org/10.1007/BF00623983