Abstract
Binuclear nickel(II) and copper(II) complexes with four 5-methoxysalicylaldehyde N(3)-substituted thiosemicarbazones and nickel(II) complexes of four 5-nitro-salicylaldehyde N(3)-substituted thiosemicarbazones have been prepared and characterized. I.r., electronic, and e.s.r. spectra of the complexes, as well as i.r., electronic, and 1H- and 13C-n.m.r spectra of the thiosemicarbazones, have been obtained. None of these compounds show significant growth inhibitory activity against the fungi Aspergillus niger and Paecilomyces variotii.
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D. X. West, S. B. Padhye, P. B. Sonawane and R. C. Chikate, Asian J. Chem. Rev. 1, 125 (1990).
D. X. West, S. B. Padhye, and P. B. Sonawane, Structure Bonding, 76, 1 (1991); D. X. West, A. E. Liberta, S. B. Padhye, R. C. Chikate, P. B. Sonawane, A. S. Kumbhar and R. G. Yerande, Coord. Chem. Rev., 123, 49 (1993).
For example, B. Singh and U. Srivastava, Synth. React. Inorg. Met-org. Chem., 19, 279 (1989); S. Laly and G. Parameswaran, Thermochim. Acta., 168, 43 (1990) and refs, cited therein.
M. Soriano-García R. A. Toscano, J. Valdés-Martínez and J. M. Fernandez-G, Acta Crystallogr. Sect., C 41, 498 (1985); L. H. Reddy, K. G. Reddy and D. V. Reddy, Proc. Ind. Sci. Acad., 55, 517 (1989).
D. X. West, Y-H. Yang, T. L. Klein, K. I. Goldberg, A. E. Liberta, J. Valdés-Martinéz and R. A. Toscano, Polyhedron, 14, 1681 (1995).
D. X. West, Y-H. Yang, T. L. Klein, K. I. Goldberg, A. E. Liberta, J. Valdés-Martinéz and S. Hernández-Ortega, Polyhedron, 14, 3051 (1995).
J. A. De Bolfo, T. D. Smith, J. F. Boas and J. R. Pilbrow, Aust. J. Chem., 29, 2583 (1976).
J. Jezierska, Asian J. Chem., 4, 189 (1992).
D. X. West, M. M. Salberg, G. A. Bain, A. E. Liberta, J. Valdés-Martínez and S. Hernández-Ortega, Transition Met. Chem., 21, 206 (1996).
B. Holmberg and B. Psilanderhielm, J. Prakt. Chem., 82, 440 (1910).
J. P. Scovill, Phosphorus, Sulfur Silicon Relat. Elem., 60, 15 (1991).
D. X. West, J. S. Saleda and A. E. Liberta, Transition Met. Chem., 17, 568 (1992) and refs cited therein.
K. R. Koch, J. Coord. Chem., 22, 289 (1991).
D. X. West, C. E. Ooms, J. S. Saleda, H. Gebremedhin and A. E. Liberta, Transition Met. Chem., 19, 553 (1994).
D. X. West, B. L. Mokijewski, H. Gebremedhin and T. J. Romack, Transition Met. Chem., 17, 384 (1992).
K. Dey and D. Bandyopadhyay, Ind. J. Chem., 31A, 34 (1992).
D. X. West, C. S. Carlson, K. J. Bouck and A. E. Liberta, Transition Met. Chem., 16, 271 (1991) and refs cited therein.
P. Sousa, J. A. Garcia-Vazquez, and J. A. Masaquer, Transition Met. Chem., 9, 318 (1984); S. K. Agarwal, D. R. Tu¯ani, R. Gupta and S. K. Hajela, Inorg. Chim. Acta, 129, 257 (1987); N. Saha and S. Sinha, Indian J. Chem., 29A, 292 (1990).
S. K. Nag and D. S. Joarder, Can. J. Chem., 54, 2827 (1976); S. K. Sengupta, S. K. Sahni and R. N. Kapoor, Acta Chim. Acad. Sci. Hungary, 104, 89 (1980); R. Roy, M. Chaudhury, S. K. Mondal and K. Nag., J. Chem. Soc., Dalton Trans., 1681 (1984); A. Z. El-Sonbati, E. M. Mabrouk, and H. E. Megahed, Transition Met. Chem., 16, 280 (1991).
J. Jezierska, B. Jezowska-Trzebiatowska and G. Petrova, Inorg. Chim. Acta, 50, 153 (1981) and refs cited therein.
H. H. Jaffé and M. Orchin, Theory and Applications of Ultraviolet Spectroscopy, Wiley, New York, 1962, p. 477.
M. Mikuriya, H. Okawa and S. Kida, Inorg. Chim. Acta, 34, 13 (1979); E. Ainscough, A. M. Brodie and N. G. Larsen, Inorg. Chim. Acta, 60, 25 (1982).
M. Mikuriya, H. Okawa and S. Kida, Bull. Chim. Soc. Jpn, 53, 3717 (1980).
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West, D.X., Salberg, M.M., Bain, G.A. et al. Nickel(II) and copper(II) complexes of 5-substituted-salicylaldehyde thiosemicarbazones. Transition Metal Chemistry 22, 180–184 (1997). https://doi.org/10.1023/A:1018431600844
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DOI: https://doi.org/10.1023/A:1018431600844