Summary
The anion (loss of3 N hydrogen) of 2-acetylpyridine4 N-methylthiosemicarbazone coordinates in a planar conformation to copper(II) through the pyridyl nitrogen, azomethine nitrogen and thiolato sulphur atoms. The fourth coordination site is occupied by a bromo ligand and the complex is mononuclear and essentially planar. Bond distances and angles, as well as solid state and solution spectral properties, are compared to other recently reported copper(II) thiosemicarbazone complexes.
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West, D.X., Gebremedhin, H., Butcher, R.J. et al. Molecular structure and spectral properties of bromo(2-acetylpyridine4 N-methylthiosemicarbazonato)copper(II). Transition Met Chem 20, 84–87 (1995). https://doi.org/10.1007/BF00135409
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DOI: https://doi.org/10.1007/BF00135409