Summary
Copper(II) and iron(III) complexes of 2-acetylpyridineN-oxide4 N-ethyl- and4 N-diethylthiosemicarbazones have been prepared and characterized by physical and spectral methods. The4 N-ethyl-derivative coordinates as a neutral, bidentate ligand with copper(II), and the4 N-diethyl- as an anionic, tridentate ligand with both copper(II) and iron(III). The former ligand forms a mixed ligand complex (i.e., one neutral and one anionic ligand) with iron(III).
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West, D.X., Borowy, L.D. Transition metal ion complexes of thiosemicarbazones derived from 2-acetylpyridineN-oxide. Part IV. Iron(III) and copper(II) complexes of the4 N-ethyl- and4 N-diethylthiosemicarbazones. Transition Met Chem 16, 5–8 (1991). https://doi.org/10.1007/BF01127860
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DOI: https://doi.org/10.1007/BF01127860