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Stabilization of cobalt(II) chloro-complexes with the butanediammonium cation

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Summary

Cobalt(II) chlorocomplexes with empirical formulae (bnH2)2CoCl6·2H2O (1) and (bnH2)2CoCl6 (2), where bnH 2+2 represents the diprotonated species of putrescine (1,4-butanediamine), were prepared.

The visible spectra in the solid state and measurement of the magnetic moments permit the assignation of an octahedral geometry for cobalt in (1) and a tetrahedral geometry for (2).

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Authors and Affiliations

  1. Departamento de Química Inorgánica, Facultad de C. Químicas, Universidad de Salamanca, España

    Miguel A. Bañares, Amador Angoso, Juan L. Manzano & Emilio Rodríguez

Authors
  1. Miguel A. Bañares
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  2. Amador Angoso
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  3. Juan L. Manzano
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  4. Emilio Rodríguez
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Bañares, M.A., Angoso, A., Manzano, J.L. et al. Stabilization of cobalt(II) chloro-complexes with the butanediammonium cation. Transition Met Chem 12, 149–152 (1987). https://doi.org/10.1007/BF01022344

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  • DOI: https://doi.org/10.1007/BF01022344

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